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Synthesis of 1,3-dithiole-2-thiones and tetrathiafulvalenes using oligo-(1,3-dithiole-2,4,5-trithione). (Review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Methods for the synthesis of 1,3-dithiole-2-thiones, based on [4+2] cycloaddition of the 1,3-dithiole-2,4,5-trithione oligomer to various unsaturated acyclic, carbocyclic, and heterocyclic compounds, are reviewed. Methods for the production of substituted tetrathiafulvalenes, which can be regarded as derivatives of bis(ethylenedithio)tetrathiafulvalene, from 1,3-dithiole-2-thiones synthesized by this method are described.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Urals Branch of the Russian Academy of Sciences, Perm, 614990, Russia

    G. G. Abashev

  2. Natural-Sciences Institute, Perm, 614990, Russia

    E. V. Shklyaeva

Authors
  1. G. G. Abashev
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  2. E. V. Shklyaeva
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Dedicated to the memory of Professor O. Neilands.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 483–502, April, 2006.

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Abashev, G.G., Shklyaeva, E.V. Synthesis of 1,3-dithiole-2-thiones and tetrathiafulvalenes using oligo-(1,3-dithiole-2,4,5-trithione). (Review). Chem Heterocycl Compd 42, 423–439 (2006). https://doi.org/10.1007/s10593-006-0107-1

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  • DOI: https://doi.org/10.1007/s10593-006-0107-1

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