Advertisement

Chemistry of Heterocyclic Compounds

, Volume 42, Issue 1, pp 92–99 | Cite as

Heterocyclic analogs of pleiadiene. 75. Formylation of perimidines and 2,2-dimethyl-2,3-dihydroperimidine under vilsmeier conditions

  • E. A. Filatova
  • I. V. Borovlev
  • A. F. Pozharskii
  • V. I. Goncharov
  • O. P. Demidov
Article

Abstract

The formylation of perimidine, its 2-and 3-methyl derivatives, and 2,2-dimethyl-2,3-dihydroperimidine has been studied under the conditions of the Vilsmeier reaction. In the last case recyclization occurs. The characteristics of the 1H NMR spectra of the aldehydes obtained are discussed.

Keywords

perimidine the Vilsmeier reaction recyclization formylation 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    I. V. Borovlev, O. M. Demidov, A. V. Aksenov, and A. F. Pozharskii, Zhur. Org. Khim., 40, 932 (2004).Google Scholar
  2. 2.
    A. F. Pozharsky, E. A. Filatova, N. V. Vistorobsky, and I. V. Borovlev, Khim. Geterotsikl. Soedin., 365 (1999).Google Scholar
  3. 3.
    V. I. Minkin, V. A Bren’, A. D. Garnovskii, and R. I. Nikitina, Khim. Geterotsikl. Soedin., 552 (1972).Google Scholar
  4. 4.
    A. F. Pozharskii, L. A. Kurasov, V. V. Kuz’menko, and G. G. Yurchuk, Zhur. Org. Khim., 18, 419 (1982).Google Scholar
  5. 5.
    A. F. Pozharskii, A. N. Suslov, N. M. Starshikov, L. L. Popova, N. A. Klyuev, and V. A. Alanin, Zhur. Org. Khim., 16, 2216 (1980).Google Scholar
  6. 6.
    A. F. Pozharskii and G. G. Yurchuk, Khim. Geterotsikl. Soedin., 418 (1979).Google Scholar
  7. 7.
    V. V. Mezheritskii, D. M. Elisevich, and G. N. Doforeenko, Zhur. Org. Khim., 17, 2444 (1981)Google Scholar
  8. 8.
    I. V. Borovlyov, A. F. Pozharskii, and V. N. Korolyova, Khim. Geterotsikl. Soedin.,1692 (1975).Google Scholar
  9. 9.
    A. F. Pozharskii, V. V. Dal’nikovskaya, S. S Pozharskaya, and A. K. Sheinkman, Khim. Geterotsikl. Soedin., 1398 (1980).Google Scholar
  10. 10.
    C. Jutz, Adv. Org. Chem., 9, 225 (1976).Google Scholar
  11. 11.
    O. Meth-Cohn, and B. Tarnowski, Adv. Heterocycl. Chem., 31, 207 (1982).Google Scholar
  12. 12.
    A. F. Pozharskii, N. V. Vistorobskii, M. I. Rudnev, and A. I. Chernyshov, Izv. Akad. Nauk, Ser. Khim., 2039 (1996).Google Scholar
  13. 13.
    A. F. Pozharskii, I. V. Borovlyov, and I. S. Kashparov, Khim. Geterotsikl. Soedin., 543 (1975).Google Scholar
  14. 14.
    E. A. Filatova, I. V. Borovlev, A. F. Pozharskii, Z. A. Starikova, and N. V. Vistorobskii, Mendeleev. Commun., 178 (2000).Google Scholar
  15. 15.
    A. F. Pozharskii, Uspekhi Khimii, 72, 498 (2003).Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • E. A. Filatova
    • 1
  • I. V. Borovlev
    • 2
  • A. F. Pozharskii
    • 1
  • V. I. Goncharov
    • 3
  • O. P. Demidov
    • 1
  1. 1.Chemistry FacultyRostov State UniversityRostov-on-DonRussia
  2. 2.Medico-biologo-chemical FacultyStavropol State UniversityStavropolRussia
  3. 3.Stavropol State Medical AcademyStavropolRussia

Personalised recommendations