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Chemistry of Heterocyclic Compounds

, Volume 42, Issue 1, pp 34–41 | Cite as

1,2-Dioximes in the trofimov reaction

  • A. B. Zaitsev
  • E. Yu. Schmidt
  • A. M. Vasil’tsov
  • A. I. Mikhaleva
  • O. V. Petrova
  • A. V. Afonin
  • N. V. Zorina
Article

Abstract

3,3′-Dimethyl-1,1′-divinyl-2,2′-dipyrrole was obtained during the reaction of 3,4-hexanedione dioximes with acetylene under pressure in the potassium hydroxide-DMSO system. In the case of 1,2-cyclohexanedione dioxime 2,2′-dipyrrole and 2-pyridyl-and 2-acylpyrroles were isolated. α-Benzil and α-furil dioximes give 3,4-diphenyl-and 3,4-di(2-furyl)-1,2,5-oxadiazoles respectively in addition to their mono-and divinyl derivatives.

Keywords

acetylene O-vinyloxime dioxime dipyrrole 1,2,5-oxadiazole pyridylpyrrole Trofimov reaction superbasic system 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • A. B. Zaitsev
    • 1
  • E. Yu. Schmidt
    • 1
  • A. M. Vasil’tsov
    • 1
  • A. I. Mikhaleva
    • 1
  • O. V. Petrova
    • 1
  • A. V. Afonin
    • 1
  • N. V. Zorina
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of ChemistrySiberian Branch of the Russian Academy of SciencesIrkutsk

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