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Chemistry of Heterocyclic Compounds

, Volume 42, Issue 1, pp 28–33 | Cite as

Transformations of sym-octahydroxanthene-1,8-diones and 1,8-dioxo-sym-octahydroxanthylium salts in recyclization under the influence of amines

  • Yu. M. Shchekotikhin
  • T. G. Nikolaeva
Article

Abstract

The chemical behavior of 9-R-sym-octahydroxanthene-1,8-diones and salts based on them in recyclization reactions under the influence of amines was studied. The effect of the basicity of the amines on the direction of recyclization was established. A method is proposed for the single-stage synthesis of sym-octahydroacridine-1.8-dione oximes based on 1,8-dioxo-sym-octahydroxanthenes. Conditions were worked out for the oxidation of sym-octahydroxanthene-1,8-diones and N-R-decahydroacridinediones to the corresponding salts.

Keywords

decahydroacridine-1,8-diones sym-octahydroacridine-1,8-dione oximes 1,8-dioxo-sym-octahydroacridinium perchlorates sym-octahydroxanthene-1,8-diones 1,8-dioxo-sym-octahydroxanthylium salts amination oxidation recyclization 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Yu. M. Shchekotikhin
    • 1
  • T. G. Nikolaeva
    • 2
  1. 1.ZAO Nita-FarmSaratovRussia
  2. 2.N. G. Chernyshevsky Saratov State UniversitySaratovRussia

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