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4,5-Dioxo-and 4-oxo-2,3-diaryl-5-diazo-6,6-dimethyl-4,5,6,7-tetrahydroindazoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The oxidation of 2,3-diphenyl-, 3-(4-chlorophenyl)-2-phenyl-, 3-(4-dimethylaminophenyl)-2-phenyl-, 3-(4-methoxyphenyl)-2-phenyl-, 2-phenyl-3-(3-pyridyl)-, 3-phenyl-2-(2-pyridyl)-, and 3-(4-dimethylaminophenyl)-6,6-dimethyl-4-oxo-2-(2-pyridyl)-4,5,6,7-tetrahydroindazoles using H2SeO3 in acetic acid in the presence of sulfuric acid gave the corresponding 4,5-dioxo derivatives. Reaction of these with tosylhydrazine gave 4-oxo-5-tosylhydrazino derivatives which were decomposed by alkali to give the corresponding 2,3-diaryl-5-diazo-6,6-dimethyl-4-oxo-4,5,6,7-tetrahydroindazoles.

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References

  1. E. Yu. Gudriniece, A. Ya. Strakov, I. A. Strakova, D. R. Zicane, and A. F. Ievin’sh, Dokl. Akad. Nauk., 216, 1293 (1974).

    CAS  Google Scholar 

  2. A. Strakov, J. Sliede, D. Zicane, and I. Strakova, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 81 (1977).

  3. I. Strakova, A. Strakovs, E. Gudriniece, and I. Svarina, Izv. Akad. Nauk. Latv. SSR, Ser. Khim., 483 (1982).

  4. I. Strakova, A. Strakov, and I.. Ribalko, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 229 (1983).

  5. I. A. Strakova, A. Ya. Strakov, and M. V. Petrova, Khim. Geterotsikl. Soedin., 351 (1995).

  6. A. Ya. Strakov, N. N. Tonkikh, M. V. Petrova, and I. A. Strakova, Khim. Geterotsikl. Soedin., 1669 (1997).

  7. I. A. Strakova, A. Ya. Strakov, M. V. Petrova, and L. G. Delyatitskaya, Khim. Geterotsikl. Soedin., 533 (2000).

  8. A. Strakov, J. Sliede, and I. Strakova, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 469 (1976).

  9. D. R. Zicane and A. Ya. Strakov, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 742 (1975).

  10. A. Ya. Strakov and M. B. Andaburskaya, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 108 (1975).

  11. N. Tonkikh, H. Duddeck, M. Petrova, O. Neilands, and A. Strakovs, Eur. J. Org. Chem., 1585 (1999).

  12. I. Strakova, A. Strakovs, and M. V. Petrova, Khim. Geterotsikl. Soedin., 1662 (2005).

  13. I. Strakova, A. Strakovs, and M. V. Petrova, Khim. Geterotsikl. Soedin., 1669 (2005).

  14. M. Cava, R. Litle, and D. Hapier, J. Amer. Chem. Soc., 80, 2257 (1958).

    CAS  Google Scholar 

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1829–1833, December, 2005

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Strakova, I., Strakovs, A. & Petrova, M. 4,5-Dioxo-and 4-oxo-2,3-diaryl-5-diazo-6,6-dimethyl-4,5,6,7-tetrahydroindazoles. Chem Heterocycl Compd 41, 1507–1510 (2005). https://doi.org/10.1007/s10593-006-0028-z

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  • DOI: https://doi.org/10.1007/s10593-006-0028-z

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