Abstract
The oxidation of 2,3-diphenyl-, 3-(4-chlorophenyl)-2-phenyl-, 3-(4-dimethylaminophenyl)-2-phenyl-, 3-(4-methoxyphenyl)-2-phenyl-, 2-phenyl-3-(3-pyridyl)-, 3-phenyl-2-(2-pyridyl)-, and 3-(4-dimethylaminophenyl)-6,6-dimethyl-4-oxo-2-(2-pyridyl)-4,5,6,7-tetrahydroindazoles using H2SeO3 in acetic acid in the presence of sulfuric acid gave the corresponding 4,5-dioxo derivatives. Reaction of these with tosylhydrazine gave 4-oxo-5-tosylhydrazino derivatives which were decomposed by alkali to give the corresponding 2,3-diaryl-5-diazo-6,6-dimethyl-4-oxo-4,5,6,7-tetrahydroindazoles.
Similar content being viewed by others
References
E. Yu. Gudriniece, A. Ya. Strakov, I. A. Strakova, D. R. Zicane, and A. F. Ievin’sh, Dokl. Akad. Nauk., 216, 1293 (1974).
A. Strakov, J. Sliede, D. Zicane, and I. Strakova, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 81 (1977).
I. Strakova, A. Strakovs, E. Gudriniece, and I. Svarina, Izv. Akad. Nauk. Latv. SSR, Ser. Khim., 483 (1982).
I. Strakova, A. Strakov, and I.. Ribalko, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 229 (1983).
I. A. Strakova, A. Ya. Strakov, and M. V. Petrova, Khim. Geterotsikl. Soedin., 351 (1995).
A. Ya. Strakov, N. N. Tonkikh, M. V. Petrova, and I. A. Strakova, Khim. Geterotsikl. Soedin., 1669 (1997).
I. A. Strakova, A. Ya. Strakov, M. V. Petrova, and L. G. Delyatitskaya, Khim. Geterotsikl. Soedin., 533 (2000).
A. Strakov, J. Sliede, and I. Strakova, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 469 (1976).
D. R. Zicane and A. Ya. Strakov, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 742 (1975).
A. Ya. Strakov and M. B. Andaburskaya, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 108 (1975).
N. Tonkikh, H. Duddeck, M. Petrova, O. Neilands, and A. Strakovs, Eur. J. Org. Chem., 1585 (1999).
I. Strakova, A. Strakovs, and M. V. Petrova, Khim. Geterotsikl. Soedin., 1662 (2005).
I. Strakova, A. Strakovs, and M. V. Petrova, Khim. Geterotsikl. Soedin., 1669 (2005).
M. Cava, R. Litle, and D. Hapier, J. Amer. Chem. Soc., 80, 2257 (1958).
Author information
Authors and Affiliations
Additional information
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1829–1833, December, 2005
Rights and permissions
About this article
Cite this article
Strakova, I., Strakovs, A. & Petrova, M. 4,5-Dioxo-and 4-oxo-2,3-diaryl-5-diazo-6,6-dimethyl-4,5,6,7-tetrahydroindazoles. Chem Heterocycl Compd 41, 1507–1510 (2005). https://doi.org/10.1007/s10593-006-0028-z
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s10593-006-0028-z