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Chemistry of Heterocyclic Compounds

, Volume 41, Issue 6, pp 722–729 | Cite as

Dioximes of 1,3-Diketones in the Trofimov Reaction: New 3-Substituted Pyrroles

  • A. B. Zaitsev
  • E. Yu. Schmidt
  • A. M. Mikhaleva
  • A. V. Afonin
  • I. A. Ushakov
Article

Abstract

Dioximes of 1,3-diketones enter into the Trofimov reaction forming pyrroles containing an acyl or an O-vinyloxime substituent in position 3 of the pyrrole. In the case of sterically hindered dioximes the main reaction products are isoxazoles.

Keywords

acetylene 3-acylpyrroles O-vinyloximes 1-vinylpyrroles dioximes of 1,3-diketones isoxazoles 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • A. B. Zaitsev
    • 1
  • E. Yu. Schmidt
    • 1
  • A. M. Mikhaleva
    • 1
  • A. V. Afonin
    • 1
  • I. A. Ushakov
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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