Chemistry of Heterocyclic Compounds

, Volume 41, Issue 3, pp 374–378 | Cite as

Pyridyl-substituted [1,3]Dithiolo-[4,5-b][1,4]dithiine-2-thiones

  • A. Yu. Koshevaya
  • V. A. Starodub
  • D. Fenske


We have obtained 5-(2-pyridyl)[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione for the first time by cycloaddition of 2-ethynylpyridine to 4,5-dihydro-1,3-dithioltrithione (isotrithionedithiol). We have studied this thione, 5-(2-pyridyl)- and 5-(4-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thiones by mass spectroscopy and also IR, UV, 1H and 13C NMR spectra. We have determined the crystal and molecular structure of 5-(2-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione.


4,5-dihydro-1,3-dithioltrithione (isotrithionedithiol) 5-(2-pyridyl)[1,3]dithiolo[4,5-b][1 4]-dithiine-2-thione 5-(2-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 5-(4-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione IR 1H and 13C NMR spectra X-ray diffraction analysis 


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© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • A. Yu. Koshevaya
    • 1
  • V. A. Starodub
    • 1
  • D. Fenske
    • 2
  1. 1.V. N. Karazin Kharkov National UniversityKharkovUkraine
  2. 2.Institute of Inorganic ChemistryTechnical University of KarlsruheKarlsruheGermany

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