Cu(imid)4SO4 - Low Dimensional S=1/2 Heisenberg Magnet
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Magnetostructural correlations have been studied in the title compound at low temperatures. The investigations included the detailed study of hydrogen bond geometry, completed by thermodynamic measurements and electron paramagnetic resonance experiment. In contrast to the expectation based on structural consideration, the investigations revealed surprisingly weak magnetic correlations which can be ascribed to the non-trivial magnetochemistry of the hydrogen bonds present in the structure.
Keywordsexchange interaction magnetosructural correlations Heisenberg magnet
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