Multi-functional finishing of cotton fabrics by water-based layer-by-layer assembly of metal–organic framework
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A multi-functional cotton fabric with UV resistance, antibacterial and superhydrophobic properties was achieved by immobilizing metal–organic framework ZnBDC on the fabric surface using zinc(II) acetate and 1,4-benzenedicarboxylic acid as raw materials. The immobilization of ZnBDC was performed via water-based layer-by-layer (LbL) deposition based on the concept of self-assemble. The ZnBDC on cotton surface was characterized by XRD, ATR-FTIR, SEM, UV–Vis spectra, TG and adsorption of Rhodamine B. The results indicated the ZnBDC was formed as a partially hydrolyzed phase of MOF-5 on the fabric surface during the LbL deposition. The porous structure of ZnBDC was kept after the deposition. The effect of deposition cycle, deposition temperature and time on the deposition of ZnBDC has been studied. The results showed that the ZnBDC deposited cotton fabric had an excellent anti-UV properties with UPF 50 +, T(UV-A) and T(UV-B) < 5%. The ZnBDC deposited cotton fabric exhibited an excellent antimicrobial effect on gram-positive bacteria Staphylococcus aureus and gram-negative bacteria Escherichia coli. The treatment of sodium stearate further imparted the superhydrophobic property on the ZnBDC deposited cotton fabric with water contact angle > 150°.
KeywordsMetal organic frameworks Layer-by-layer deposition Cotton UV resistance Antibacterial Superhydrophobic
This work was supported by the National Science and Technology Ministry (ID2012BAK30B03) and the Fundamental Research Funds for the Central Universities and the Central Universities (No. 2232013A3-05).
- Abbasi A, Akhbari K, Morsali A (2012) Dense coating of surface mounted CuBTC metal–organic framework nanostructures on silk fibers, prepared by layer-by-layer method under ultrasound irradiation with antibacterial activity. Ultrason Sonochem 19(4):846–852. https://doi.org/10.1016/j.ultsonch.2011.11.016 CrossRefPubMedGoogle Scholar
- Cheng YN, Xiao LW, Li HL, Ye Z (2015) Concentration ranges of antibacterial cations for showing the highest antibacterial efficacy but the least cytotoxicity against mammalian cells: implications for a new antibacterial mechanism. Chem Res Toxicol 28(9):1815–1822. https://doi.org/10.1021/acs.chemrestox.5b00258 CrossRefGoogle Scholar
- Hafizovic J, Bjørgen M, Olsbye U, Dietzel PDC, Bordiga S, Prestipino C, Lamberti C, Lillerud KP (2007) The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities. J Am Chem Soc 129(12):3612–3620. https://doi.org/10.1021/ja0675447 CrossRefPubMedGoogle Scholar
- Hermes S, Schröder F, Chelmowski R, Wöll C, Fischer RA (2005) Selective nucleation and growth of metal–organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au (111). J Am Chem Soc 127(40):13744–13745. https://doi.org/10.1021/ja053523l CrossRefPubMedGoogle Scholar
- Hwang YK, Hong DY, Chang JS, Jhung S, Seo Y, Kim J, Vimont A, Daturi M, Serre C, Ferey G (2008) Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation. Angew Chem Int Ed Engl 47(22):4144–4148. https://doi.org/10.1002/anie.200705998 CrossRefPubMedGoogle Scholar
- Kaewprasit C, Hequet E, Abidi N, Gourlot JP (1998) Application of methylene blue adsorption to cotton fiber specific surface area measurement: Part I. Methodology. J Cotton Sci 2(4):164–173Google Scholar
- Lopez-Maya E, Montoro C, Rodriguez-Albelo L, Cervantes S, Lozano-Pérez A, Cenís J, Barea E, Navarro J (2015) Textile/metal–organic-framework composites as self-detoxifying filters for chemical-warfare agents. Angew Chem Int Ed Engl 54(23):6790–6794. https://doi.org/10.1002/anie.201502094 CrossRefPubMedGoogle Scholar
- Mcdonald R (1997) Color physics for industry, 2nd edn. Society of Dyers and Colorists, BradfordGoogle Scholar
- Pan Q, Zhi MS, De J, Wang X, Wu Z, Liu ZD (2013) Application of two reactive water-soluble antibacterials on polyester/cotton blend fabrics. Adv Mater Res 821–822:642–645. https://doi.org/10.4028/www.scientific.net/AMR.821-822.642 CrossRefGoogle Scholar
- Paul R (2014) Functional finishes for textiles: improving comfort, performance and protection. Woodhead Publishing, CambridgeGoogle Scholar
- Zhao J, Gong B, Nunn W, Lemaire P, Stevens E, Sidi F, Williams P, Oldham C, Walls H, Shepherd S, Browe M, Peterson G, Losego M, Parsons G (2015) Conformal and highly adsorptive metal–organic framework thin films via layer-by-layer growth on ALD-coated fiber mats. J Mater Chem A 3(4):1458–1464. https://doi.org/10.1039/C4TA05501B CrossRefGoogle Scholar