Cellulose

, Volume 25, Issue 1, pp 391–398 | Cite as

Bamboo cellulose-derived cellulose acetate for electrospun nanofibers: synthesis, characterization and kinetics

Original Paper
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Abstract

Catalysts play a key role in the production of cellulose acetate (CA). In this study, CA derived from bamboo cellulose (BC) was synthesized in a solution mixture of acetic acid and acetic anhydride that contains catalysts. The catalytic activities of three catalysts (i.e., sulfuric, methyl benzene sulfonic, and dodecyl benzene sulfonic acids) were investigated in terms of kinetics of acetylation, which was established according to the first-order reaction mechanism. Based on this, cellulose-based nanofibers were further prepared from the acetylated BC solution using an electrospinning technique. Results in this study may be useful for the preparation and application of nanomaterials derived from natural polymeric materials.

Keywords

Cellulose Electrospinning Nanofiber 

Notes

Acknowledgments

This work has been supported by the Natural Science Foundation of Hubei Province of China (No. 2017CFB198), the Science and Technology Research Project of Hubei Provincial Department of Education (No. Q20161701), the Talent Introduction Foundation of Wuhan Polytechnic University (China) (No. 2016RZ22), and Huazhong Agricultural University Scientific & Technological Selfinnovation Foundation (No. 2012SC21). Jie Cai also thanks the Chutian Scholar Program of Hubei Provincial Government, China.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interests.

References

  1. Barud HS, Júnior AMDA, Santos DB et al (2008) Thermal behavior of cellulose acetate produced from homogeneous acetylation of bacterial cellulose. Thermochim Acta 471:61–69CrossRefGoogle Scholar
  2. Cai J, Chen J, Zhang Q et al (2016a) Well-aligned cellulose nanofiber-reinforced polyvinyl alcohol composite film: mechanical and optical properties. Carbohydr Polym 140:238–245CrossRefGoogle Scholar
  3. Cai J, Zhang Q, Lei M et al (2016b) The use of solvent-soaking treatment to enhance the anisotropic mechanical properties of electrospun nanofiber membranes for water filtration. RSC Adv 6:66807–66813CrossRefGoogle Scholar
  4. Cai J, Lei M, Zhang Q et al (2017a) Electrospun composite nanofiber mats of cellulose@organically modified montmorillonite for heavy metal ion removal: design, characterization, evaluation of absorption performance. Compos Part A Appl Sci Manuf 92:10–16CrossRefGoogle Scholar
  5. Cai J, Niu H, Yu Y et al (2017b) Effect of solvent treatment on morphology, crystallinity and tensile properties of cellulose acetate nanofiber mats. J Text Inst 108:555–561CrossRefGoogle Scholar
  6. Chen W, Yu H, Liu Y et al (2011) Isolation and characterization of cellulose nanofibers from four plant cellulose fibers using a chemical-ultrasonic process. Cellulose 18:433–442CrossRefGoogle Scholar
  7. Chen C, Cho M, Nam JD, Lee Y (2013) Cellulose diacetate reinforced with electrospun cellulose fiber: a new route to prepare an all cellulose-based composite. Compos Part A Appl Sci Manuf 53:10–15CrossRefGoogle Scholar
  8. Danwanichakul P, Danwanichakul D (2014) Two-dimensional simulation of electrospun nanofibrous structures: connection of experimental and simulated results. J Chem 2014(1):1–10CrossRefGoogle Scholar
  9. Deng L, Young RJ, Kinloch IA et al (2013) Carbon nanofibres produced from electrospun cellulose nanofibres. Carbon 58:66–75CrossRefGoogle Scholar
  10. Du J (2006) Catalysts for esterification of cellulose and its application (Master's Dagree Dissertation). Donghua University, Shanghai (in Chinese)Google Scholar
  11. Hameed BH, Din AT, Ahmad AL (2007) Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies. J Hazard Mater 141:819–825CrossRefGoogle Scholar
  12. He J, Cui S, Wang S (2008) Preparation and crystalline analysis of high-grade bamboo dissolving pulp for cellulose acetate. J Appl Polym Sci 107:1029–1038Google Scholar
  13. Huang W, Zhan Y, Shi X et al (2017) Controllable immobilization of naringinase on electrospun cellulose acetate nanofibers and their application to juice debittering. Int J Biol Macromol 98:630–636CrossRefGoogle Scholar
  14. Kalia S, Dufresne A, Cherian BM et al (2011) Cellulose-based bio- and nanocomposites: a review. Int J Polym Sci 2011:2341–2348Google Scholar
  15. Khan RA, Khan MA, Zaman HU et al (2010) Comparative studies of mechanical and interfacial properties between jute and E-glass fiber-reinforced polypropylene composites. J Reinf Plast Compos 29:1078–1088CrossRefGoogle Scholar
  16. Kuzmenko V, Naboka O, Gatenholm P, Enoksson P (2014) Ammonium chloride promoted synthesis of carbon nanofibers from electrospun cellulose acetate. Carbon 67:694–703CrossRefGoogle Scholar
  17. Larik SA, Khatri A, Ali S et al (2015) Batchwise dyeing of bamboo cellulose fabric with reactive dye using ultrasonic energy. Ultrason Sonochem 24:178–183CrossRefGoogle Scholar
  18. Li XF, Chen QH, Lin JH (2008) Acetylation of chinese bamboo flour and thermoplasticity. J For Res 19:69–71CrossRefGoogle Scholar
  19. Li L, Mun Lee P, Yang G, Liu E (2015) A review on electrospun nanofibers-based electrochemical sensor. Curr Nanosci 11:710–721CrossRefGoogle Scholar
  20. Liu Q, Hao W, Yang Y et al (2014) Effects of size and dispersity of microcrystalline celluloses on size, structure and stability of nanocrystalline celluloses extracted by acid hydrolysis. Nano Life 4:1441014CrossRefGoogle Scholar
  21. Lu P, Hsieh YL (2010) Multiwalled carbon nanotube (MWCNT) reinforced cellulose fibers by electrospinning. ACS Appl Mater Interfaces 2:2413–2420CrossRefGoogle Scholar
  22. Minnick DL, Flores RA, Destefano MR et al (2016) Cellulose solubility in ionic liquid mixtures: temperature, cosolvent and antisolvent effects. J Phys Chem B 120:7906–7916CrossRefGoogle Scholar
  23. Obataya E, Minato K (2007) Effects of previous solvent exchange on acetylation of wood. Wood Sci Technol 41:351–360CrossRefGoogle Scholar
  24. Olyveira GM, Acasigua GA, Costa LM et al (2013) Human dental pulp stem cell behavior using natural nanotolith/bacterial cellulose scaffolds for regenerative medicine. J Biomed Nanotechnol 9:1370–1377CrossRefGoogle Scholar
  25. Rwawiire S, Tomkova B, Militky J et al (2015) Development of a biocomposite based on green epoxy polymer and natural cellulose fabric (bark cloth) for automotive instrument panel applications. Compos Part B Eng 81:149–157CrossRefGoogle Scholar
  26. Scurlock JMO, Dayton DC, Hames B (2000) Bamboo: an overlooked biomass resource? Biomass Bioenergy 19:229–244CrossRefGoogle Scholar
  27. Sun Y, Lin L, Deng H, Li J (2008) Structural changes of bamboo cellulose in formic acid. BioResources 3:297–315Google Scholar
  28. Teli MD, Sheikh J (2012) Graft copolymerization of acrylamide onto bamboo rayon and fibre dyeing with acid dyes. Iran Polym J 21:43–49CrossRefGoogle Scholar
  29. Tingaut P, Zimmermann T, Lopezsuevos F (2010) Synthesis and characterization of bionanocomposites with tunable properties from poly (lactic acid) and acetylated microfibrillated cellulose. Biomacromolecules 11:454–464CrossRefGoogle Scholar
  30. Yang Z, Xu S, Ma X, Wang S (2008) Characterization and acetylation behavior of bamboo pulp. Wood Sci Technol 42:621–632CrossRefGoogle Scholar

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© Springer Science+Business Media B.V., part of Springer Nature 2017

Authors and Affiliations

  1. 1.School of Food Science and EngineeringWuhan Polytechnic UniversityWuhanChina
  2. 2.College of Food Science and TechnologyHuazhong Agricultural UniversityWuhanChina
  3. 3.School of Chemical and Environmental EngineeringWuhan Polytechnic UniversityWuhanChina

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