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Cellulose

, Volume 25, Issue 1, pp 77–85 | Cite as

A green Pickering emulsion stabilized by cellulose nanocrystals via RAFT polymerization

  • Beifang Liu
  • Dongcheng Yang
  • Hong Man
  • Yongquan Liu
  • Hou Chen
  • Hui Xu
  • Wenxiang Wang
  • Liangjiu Bai
Original Paper

Abstract

As environmental-friendly and renewable materials, cellulose nanocrystals (CNCs), has great potential for replacing the poisonous chemicals. Herein, we investigate a green Pickering emulsion stabilized of CNCs by using reversible addition-fragmentation chain transfer (RAFT) polymerization. The preparation of polymethyl methacrylate (PMMA) with controlled molecular weights and low M w/M n values were successfully synthesized by the Pickering emulsion. Moreover, the well-defined PMMA can be obtained in Pickering emulsion with “green” CNCs as a sole emulsifier and the used CNCs are easy to recycle and reuse.

Keywords

Cellulose nanocrystals RAFT-mediated Pickering emulsion PMMA 

Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 51573075, 21404052 and 21404051), the Natural Science Foundation of Shandong Province (No. ZR2014BQ016), the Project of Shandong Province Higher Educational Science (No. J16LC20) and Technology Program and the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province.

References

  1. Afzali A, Buchwalter SL, Buchwalter LP, Hougham G (1997) Reaction of polyaniline with NMP at elevated temperatures. Polymer 38:4439–4443.  https://doi.org/10.1016/s0032-3861(96)1041-5 CrossRefGoogle Scholar
  2. Aveyard R, Binks BP, Clint JH (2003) Emulsions stabilised solely by colloidal particles. Adv Colloid Interface 100:503–546.  https://doi.org/10.1016/s0001-8686(02)00069-6 CrossRefGoogle Scholar
  3. Bondeson D, Mathew A, Oksman K (2006) Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis. Cellulose 13:171–180.  https://doi.org/10.1007/s10570-006-9061-4 CrossRefGoogle Scholar
  4. Capron I, Cathala B (2013) Surfactant-free high internal phase emulsions stabilized by cellulose nanocrystals. Biomacromolecules 14:291–296.  https://doi.org/10.1021/bm301871k CrossRefGoogle Scholar
  5. Chakrabarty A, Zhang L, Cavicchi KA, Weiss RA, Singha NK (2015) Tailor-made fluorinated copolymer/clay nanocomposite by cationic RAFT assisted Pickering miniemulsion polymerization. Langmuir 31:12472–12480.  https://doi.org/10.1021/acs.langmuir.5b01799 CrossRefGoogle Scholar
  6. Chakrabarty A, Ponnupandian S, Naskar K, Singha NK (2016) Nanoclay stabilized Pickering miniemulsion of fluorinated copolymer with improved hydrophobicity via RAFT polymerization. RSC Adv 6:34987–34995.  https://doi.org/10.1039/C5RA25808A CrossRefGoogle Scholar
  7. Chang HB, Luo J, Liu HC, Davijani AAB, Wang PH, Lolov GS, Dwyer RM, Kumar S (2017) Ductile polyacrylonitrile fibers with high cellulose nanocrystals loading. Polymer 122:332–339.  https://doi.org/10.1016/j.polymer.2017.06.072 CrossRefGoogle Scholar
  8. Chen H, Liang Y, Wang ML, Lv PL, Xuan YH (2009) Reverse ATRP of ethyl acrylate with ionic liquids as reaction medium. Chem Eng J 147:297–301.  https://doi.org/10.1016/j.cej.2008.11.007 CrossRefGoogle Scholar
  9. Cranston ED, Gray DG (2006) Morphological and optical characterization of polyelectrolyte multilayers incorporating nanocrystalline cellulose. Biomacromolecules 7:2522–2530.  https://doi.org/10.1021/bm0602886 CrossRefGoogle Scholar
  10. Cunningham MF (2016) Editorial for special issue: controlled radical polymerization in dispersed media. Polymer 106:159–160.  https://doi.org/10.1016/j.polymer.2016.09.091 CrossRefGoogle Scholar
  11. Dong XM, Revol JF, Gray DG (1998) Effect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose. Cellulose 5(1):19–32.  https://doi.org/10.1023/A:100926051 CrossRefGoogle Scholar
  12. Dufresne A (2013) Nanocellulose: a new ageless bionanomaterial. Mater Today 16:220–227.  https://doi.org/10.1016/j.mattod.2013.06.004 CrossRefGoogle Scholar
  13. Gong X, Wang Y, Chen L (2017) Enhanced emulsifying properties of wood-based cellulose nanocrystals as Pickering emulsion stabilizer. Carbohydr Polym 169:295–303.  https://doi.org/10.1016/j.carbpol.2017.04.024 CrossRefGoogle Scholar
  14. Hu Z, Marway HS, Kasem H, Pelton R, Cranston ED (2016) Dried and redispersible cellulose nanocrystal Pickering emulsions. ACS Macro Lett 5:185–189.  https://doi.org/10.1021/acsmacrolett.5b00919 CrossRefGoogle Scholar
  15. Kalashnikova I, Bizot H, Cathala B, Capron I (2011) New Pickering emulsions stabilized by bacterial cellulose nanocrystals. Langmuir 27:7471–7479.  https://doi.org/10.1021/la200971f CrossRefGoogle Scholar
  16. Kalashnikova I, Bizot H, Cathala B, Capron I (2012) Modulation of cellulose nanocrystals amphiphilic properties to stabilize oil/water interface. Biomacromolecules 13:267–275.  https://doi.org/10.1021/bm201599j CrossRefGoogle Scholar
  17. Kargarzadeh H, Sheltami RM, Ahmad I, Abdullah I, Dufresne A (2015) Cellulose nanocrystal: a promising toughening agent for unsaturated polyester nanocomposite. Polymer 56:346–357.  https://doi.org/10.1016/j.polymer.2014.11.054 CrossRefGoogle Scholar
  18. Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Edit 50:5438–5466.  https://doi.org/10.1002/anie.201001273 CrossRefGoogle Scholar
  19. Kovacs T, Naish V, O’Connor B, Blaise C, Gagné F, Hall L, Trudeau V, Martel P (2010) An ecotoxicological characterization of nanocrystalline cellulose (NCC). Nanotoxicology 4:255–270.  https://doi.org/10.3109/17435391003628713 CrossRefGoogle Scholar
  20. Leal-Calderon F, Schmitt V (2008) Solid-stabilized emulsions. Curr Opin Colloid Interface Sci 13:217–227.  https://doi.org/10.1016/j.cocis.2007.09.005 CrossRefGoogle Scholar
  21. Lin N, Dufresne A (2014a) Nanocellulose in biomedicine: current status and future prospect. Eur Polym J 59:302–325.  https://doi.org/10.1016/j.eurpolymj.2014.07.025 CrossRefGoogle Scholar
  22. Lin N, Dufresne A (2014b) Surface chemistry, morphological analysis and properties of cellulose nanocrystals with gradiented sulfation degrees. Nanoscale 6:5384–5393.  https://doi.org/10.1039/c3nr06761k CrossRefGoogle Scholar
  23. Lin N, Chen Y, Hu F, Huang J (2015) Mechanical reinforcement of cellulose nanocrystals on biodegradable microcellular foams with melt-compounding process. Cellulose 22:2629–2639.  https://doi.org/10.1007/s10570-015-0684-1 CrossRefGoogle Scholar
  24. Lin N, Gèze A, Wouessidjewe D, Huang J, Dufresne A (2016) Biocompatible double-membrane hydrogels from cationic cellulose nanocrystals and anionic alginate as complexing drugs codelivery. ACS Appl Mater Interfaces 8:6880–6889.  https://doi.org/10.1021/acsami.6b00555 CrossRefGoogle Scholar
  25. Liu X, Chen H, Wang CH, Qu RJ, Ji CN, Sun CM, Zhang Y (2010) Synthesis of porous acrylonitrile/methyl acrylate copolymer beads by suspended emulsion polymerization and their adsorption properties after amidoximation. J Hazard Mater 175:1014–1021.  https://doi.org/10.1016/j.jhazmat.2009.10.111 CrossRefGoogle Scholar
  26. Mascheroni E, Rampazzo R, Ortenzi MA, Piva G, Bonetti S, Piergiovanni L (2016) Comparison of cellulose nanocrystals obtained by sulfuric acid hydrolysis and ammonium persulfate, to be used as coating on flexible food-packaging materials. Cellulose 23:779–793.  https://doi.org/10.1007/s10570-015-0853-2 CrossRefGoogle Scholar
  27. Miao C, Hamad WY (2016) Alkenylation of cellulose nanocrystals (CNC) and their applications. Polymer 101:338–346.  https://doi.org/10.1016/j.polymer.2016.08.099 CrossRefGoogle Scholar
  28. Mikulcová V, Bordes R, Kašpárková V (2016) On the preparation and antibacterial activity of emulsions stabilized with nanocellulose particles. Food Hydrocoll 61:780–792.  https://doi.org/10.1016/j.foodhyd.2016.06.031 CrossRefGoogle Scholar
  29. Palmiero UC, Chovancová A, Cuccato D, Storti G, Lacík I, Moscatelli D (2016) The RAFT copolymerization of acrylic acid and acrylamide. Polymer 98:156–164.  https://doi.org/10.1016/j.polymer.2016.06.024 CrossRefGoogle Scholar
  30. Peng L, Meng Y, Li H (2016) Facile fabrication of superhydrophobic paper with improved physical strength by a novel layer-by-layer assembly of polyelectrolytes and lignosulfonates-amine. Cellulose 23:1–13.  https://doi.org/10.1007/s10570-016-0910-5 CrossRefGoogle Scholar
  31. Pickering SU (1907) The chemistry of bordeaux mixture. J Chem Soc Trans 91:1988–2001.  https://doi.org/10.1039/ct9079101988 CrossRefGoogle Scholar
  32. Siqueira G, Bras J, Dufresne A (2010) Cellulosic bionanocomposites: a review of preparation, properties and applications. Polymers 2:728–765.  https://doi.org/10.3390/polym2040728 CrossRefGoogle Scholar
  33. Sousa AF, Ferreira S, Lopez A, Borges I, Pinto RJB, Silvestre AJD, Freire CSR (2017) Thermosetting AESO-bacterial cellulose nanocomposite foams with tailored mechanical properties obtained by Pickering emulsion templating. Polymer 118:127–134.  https://doi.org/10.1016/j.polymer.2017.04.073 CrossRefGoogle Scholar
  34. Tasset S, Cathala B, Bizot H, Capron I (2013) Versatile cellular foams derived from CNC-stabilized Pickering emulsions. RSC Adv 4:893–898.  https://doi.org/10.1039/C3RA45883K CrossRefGoogle Scholar
  35. Tonnar J, Lacroix-Desmazes P (2016) Controlled radical polymerization of styrene by iodine transfer polymerization (ITP) in ab initio emulsion polymerization. Polymer 106:267–274.  https://doi.org/10.1016/j.polymer.2016.08.031 CrossRefGoogle Scholar
  36. Wei ZJ, Wang CY, Zou SW, Liu H, Tong Z (2012) Chitosan nanoparticles as particular emulsifier for preparation of novel pH-responsive Pickering emulsions and PLGA microcapsules. Polymer 53:1229–1235.  https://doi.org/10.1016/j.polymer.2012.02.015 CrossRefGoogle Scholar
  37. Wu J, Jiang HJ, Zhang LF, Cheng ZP, Zhu XL (2016) Synthesis of amphiphilic nanoparticles and multi-block hydrophilic copolymers by a facile and effective “living” radical polymerization in water. Polym Chem 7:2486–2491.  https://doi.org/10.1039/C6PY00199H CrossRefGoogle Scholar
  38. Xu WL, Cheng ZP, Zhang LF, Zhang ZB, Zhu J, Zhou NC, Zhu XL (2010) Synthesis and properties of crosslinked chiral nanoparticles via RAFT miniemulsion polymerization. J Polym Sci Pol Chem 48:1324–1331.  https://doi.org/10.1002/pola.23893 CrossRefGoogle Scholar
  39. Yang X, Shi K, Zhitomirsky I, Cranston ED (2015) Cellulose nanocrystal aerogels as universal 3D lightweight substrates for supercapacitor materials. Adv Mater 27:6104–6109.  https://doi.org/10.1002/adma.201502284 CrossRefGoogle Scholar
  40. Zhu G, Zhang L, Pan X, Zhang W, Cheng Z, Zhu X (2012) Facile soap-free miniemulsion polymerization of methyl methacrylate via reverse atom transfer radical polymerization. Macromol Rapid Commun 33:2121–2126.  https://doi.org/10.1002/marc.201200492 CrossRefGoogle Scholar
  41. Zong G, Chen H, Qu RJ, Wang C, Ji N (2011) Synthesis of polyacrylonitrile-grafted cross-linked N-chlorosulfonamidated polystyrene via surface-initiated ARGET ATRP, and use of the resin in mercury removal after modification. J Hazard Mater 186:614–621.  https://doi.org/10.1016/j.jhazmat.2010.11.043 CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2017

Authors and Affiliations

  1. 1.School of Chemistry and Materials ScienceLudong UniversityYantaiChina

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