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Cellulose

, Volume 22, Issue 4, pp 2811–2824 | Cite as

Non-formaldehyde, crease-resistant modification of cellulosic material by means of an organotrialkoxysilane and metal alkoxides

  • Christian Schramm
  • Beate Rinderer
Original Paper

Abstract

Cellulosic material is chemically modified to impart crease-resistant properties to textile products. Due to health considerations formaldehyde-free chemicals are preferred. For this purpose, (3-glycidyloxy)propyltrimethoxysilane (GPTMS) in combination with metal alkoxides aluminium isopropoxide (AIP), titanium tetraisopropoxide (TTP), zircon tetrabutoxide (ZTB) were applied to cotton raw material and cotton fabrics which were pre-treated with butane-1,2,3,4-tetracarboxylic acid (BTCA)/sodium hypophosphite. The as-prepared samples were tested for dry crease recovery angle, tensile strength, tear strength, air permeability, contact angle and whiteness index. The application of GPTMS/AIP resulted in excellent crease resistance values, whereas TTP and ZTB provided a moderate improvement of the wrinkle resistance. The application of the hydrophobic methyltriethoxysilane, octyltriethoxysilane and Dynasylan F8815 (fluoroalkylfunctional water-borne oligosiloxane) caused a significant increase in the contact angle. Fourier-transform-infrared spectroscopy proved the formation of an ester-linkage between BTCA and the cellulose.

Keywords

Cotton Crease resistance Sol–gel Organic–inorganic hybrid Wettability 

Notes

Acknowledgments

The authors would like to thank the Testing Institute of the HTL Dornbirn (Austria) for making available textile-physical devices.

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Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  1. 1.Research Institute of Textile Chemistry and Textile PhysicsUniversity InnsbruckDornbirnAustria

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