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Cellulose

, Volume 19, Issue 2, pp 481–493 | Cite as

Tryptophan-based peptides grafted onto oxidized nanocellulose

  • Saïd Barazzouk
  • Claude Daneault
Article

Abstract

Oxidized nanocellulose (ONC) have been synthesized and grafted with tryptophan-based peptides of varying lengths using a two step coupling method. The ONC was first activated by N-ethyl-N′-(3-dimethylaminopropyl) carbodiimide hydrochloride, forming a stable active ester in the presence of N-hydroxysuccinimide. Then, the active ester was reacted with the amino groups of the peptide forming an amide bond between ONC and peptide. Using this method, the intermolecular connection of Trp-based peptides (Trp-Ps) was avoided and uniform coupling of peptides on ONC was achieved. The coupling reaction was very fast in mild conditions and without alteration of the polysaccharide. The obtained products (ONC-Trp-Ps) were characterized by transmission electron microscopy and by different spectroscopic techniques.

Keywords

Oxidized nanocellulose Trp-based peptides Amide bond Spectroscopic characterization 

Notes

Acknowledgments

The authors thank the Natural Sciences and Engineering Research Council of Canada for financial support of this work.

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Copyright information

© Springer Science+Business Media B.V. 2011

Authors and Affiliations

  1. 1.Centre de Recherche sur les Matériaux LignocellulosiquesUniversité du Québec à Trois-RivièresTrois-RivièresCanada

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