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Synthesis of Diblock Copolymers With Cellulose Derivatives. 2. Characterization and Thermal Properties of Cellulose Triacetate-Block-Oligoamide-15

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Abstract

Well-defined A-block-B type cellulose derivatives consisting of cellulose triacetate (CTA) and oligoamide-15 were synthesized. Chemical structures of the diblock copolymers were characterized by MALDI-TOF MS, 1H-NMR, and GPC. Influence of length of CTA and oligoamide-15 segments on their thermal properties was investigated by means of differential scanning calorimetry (DSC). All diblock copolymers displayed T g, T c, and T m transition temperatures. Their T g and T m values increased with the increase of molecular weight of CTA segment. The crystallinity of diblock copolymers increased after isothermal crystallization at 200 °C. Its X-ray analysis revealed that the diblock copolymer had CTA II crystal structure. Thermal analysis supported microphase separation between CTA and oligoamide-15 segments at room temperature, because T g and T m values of polyamide-15 are −7 °C and 170–180 °C, respectively.

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Abbreviations

CTA:

Cellulose triacetate

GPC:

Gel permeation chromatography

MALDI-TOF MS:

Matrix assisted laser desorption/ionization time-of-flight mass spectroscopy

DSC:

differential scanning calorimetry

DPn :

Number-average degree of polymerization

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Authors and Affiliations

  1. Graduate School of Agriculture, Kyoto University, Kitashirakawaoiwake-cho, Sakyo-ku, Kyoto, 606-8502, Japan

    Hiroshi Kamitakahara, Yukiko Enomoto, Chinatsu Hasegawa &  Fumiaki Nakatsubo

Authors
  1. Hiroshi Kamitakahara
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  2. Yukiko Enomoto
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  3. Chinatsu Hasegawa
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  4. Fumiaki Nakatsubo
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Correspondence to Hiroshi Kamitakahara.

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Kamitakahara, H., Enomoto, Y., Hasegawa, C. et al. Synthesis of Diblock Copolymers With Cellulose Derivatives. 2. Characterization and Thermal Properties of Cellulose Triacetate-Block-Oligoamide-15. Cellulose 12, 527–541 (2005). https://doi.org/10.1007/s10570-005-7135-3

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  • DOI: https://doi.org/10.1007/s10570-005-7135-3

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