Abstract
Simple and convenient methods for determining surface chemical composition of lignocellulosic materials are described. The methods are based on vapor phase fluorine surface derivatization with either trifluoro acetic anhydride (TFAA), tri-fluoro ethanol (TFE) or pentafluorophenyl hydrazine (PFPH) and subsequent Electron Spectroscopy for Chemical Analysis (ESCA). Model cellulosic surfaces with well defined functionalities were used to optimize the derivatization reaction conditions. Detection and accessibility of surface hydroxyl functional groups were investigated in cotton and regenerated cellulose as models. Carboxymethyl cellulose (CMC) was used as a model surface for detection and quantification of carboxylic acid groups. Theoretical conversion curves for derivatization reactions were calculated and used to evaluate the extent of the reactions on the model surfaces. It was found that the conversion was higher for the regenerated cellulose and CMC than for cotton. The protocols developed using the model surfaces were applied to a case study on wood fibers with different degrees of complexity, namely dissolving and chemithermomechanical (CTMP) pulp. Untreated and oxygen-plasma modified pulps were compared with respect to the surface composition of functional groups. According to the derivatization reactions, functionalities containing oxygen were significantly increased on the plasma-treated samples. The effect of the treatment was found to be dependent on the type of pulp. Fluorine derivatization is shown to be an unambiguous method for clear assessment of the chemical functionalities of cellulosic surfaces.
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J.D. Andrade, Surface and Interfacial Aspects of Biomedical Polymers, Vol.1: Surface Chemistry and Physics. New York, NY: Plenum Press (1985).
C.D. Batich, Chemical derivatization and surface analysis. Appl. Surf. Sci. 32 (1988) 57-73
M.N. Belgacem, G. Czeremuszkin, S. Sapieha and A. Gandini, Surface characterization of cellulose fibres by XPS and inverse gas chromatography. Cellulose 2 (1995) 145-157
G. Buschle-Diller and S.H. Zeronian, Enhancing the reactivity and strength of cotton fibers. J. Appl. Polym. Sci. 45 (1992) 967-79
L. Börås and P. Gatenholm, Surface composition and morphology of CTMP fibers. Holzforschung 53 (1999) 188-194
C.M.G. Carlsson and G. Ström, Reduction and oxidation of cellulose surfaces by means of cold plasma. Langmuir 7 (1991) 2492-2497
C.M.G. Carlsson, G. Ström and G. Annergren, Water sorption and surface composition of untreated or oxygen plasma-treated chemical pulps. Nordic Pulp Paper Res. J. 10 (1995) 17-23
C.M.G. Carlsson, G. Ström, I. Eriksson and E. Lindström, Improved wettability of chemithermomechanical pulp by oxygen plasma treatment. Nordic Pulp Paper Res. J. 9 (1994) 72-83
A. Chilkoti, D.G. Castner, B.D. Ratner and D. Briggs, Surface characterization of a poly(styrene/p-hydroxystyrene) copolymer series using x-ray photoelectron spectroscopy, static secondary ion mass spectrometry, and chemical derivatization techniques. J. Vacuum Sci. Technol. A8 (1990) 2274-2282
A. Chilkoti and B.D. Ratner, An X-ray photoelectron spectroscopic investigation of the selectivity of hydroxyl derivatization reactions. Surface Interface Analysis 17 (1991) 567-574
A. Chilkoti, B.D. Ratner and D. Briggs, Plasma-deposited polymeric films prepared from carbonyl-containing volatile precursors: XPS chemical derivatization and static SIMS surface characterization. Chem. Mat. 3 (1991) 51-61
T.E. Conners and S. Banerjee, Surface Analysis of Paper. Boca Raton: CRC Press (1995).
R.A. Dickie, J.S. Hammond, J.E. Vries de and J.W. Holubka, Surface derivatization of hydroxyl functional acrylic copolymers for characterization by X-ray photoelectron spectroscopy. Anal. Chem. 54 (1982) 2045-2049
G.M. Dorris and D.G. Gray, The surface analysis of paper and wood fibers by ESCA (electron spectroscopy for chemical analysis). I. Application to cellulose and lignin. Cell. Chem. Technol. 12 (1978a) 9-23
G.M. Dorris and D.G. Gray, The surface analysis of paper and wood fibers by ESCA. II. Surface composition of mechanical pulps. Cell. Chem. Technol. 12 (1978b) 721-734
D.S. Everhart and C.N. Reilley, Chemical derivatization in electron spectroscopy for chemical analysis of surface functional groups introduced on low-density polyethylene film. Anal. Chem. 53 (1981) 665-676
J.M. Felix and P. Gatenholm, The nature of adhesion in composites of modified cellulose fibers and polypropylene. J. Appl. Polym. Sci. 42 (1991) 609-620
D. Fengel and G. Wegener, Wood: Chemistry, UltrastructureReactions. Berlin, New York: Walter de Gruyter (1989).
F Garbassi, M. Morra and E. Occhiello, Polymer Surface: From Physics to Technology. Chichester, England: John Wiley and Sons (1998).
F. Gellerstedt and P. Gatenholm, Surface properties of lignocellulosic fibers bearing carboxylic groups. Cellulose 6 (1999) 103-121
L.J. Gerenser, J.F. Elman, M.G. Mason and J.M. Pochan, ESCA studies of corona-discharge-treated polyethylene surfaces by use of gas-phase derivatization. Polymer 26 (1985) 1162-1166
D.A.I. Goring, Surface modification of cellulose in a corona discharge. Pulp Paper Magazine Canada 68 (1967) T372-T376
D.G. Gray, The surface analysis of paper and wood fibers by ESCA. III. Interpretation of carbon (1s) peak shape. Cell. Chem. Technol. 12 (1978) 735-743
Å. Henriksson and P. Gatenholm, Controlled assembly of glucuronoxylans onto cellulose fibers. Holzforschung 55 (2001) 494-502
Z.Q. Hua, R. Sitaru, F. Denes and R. A. Young, Mechanisms of oxygen- and argon-RF-plasma-induced surface chemistry of cellulose. Plasmas and Polymers 2 (1997) 199-224
D.A. Hutt and G.J. Leggett, Functionalization of hydroxyl and carboxylic acid terminated self-assembled monolayers. Langmuir 13 (1997) 2740-2748
K. Koljonen, M. Osterberg, L.S. Johansson and P. Stenius, Surface chemistry and morphology of different mechanical pulps determined by ESCA and AFM. Colloids and Surfaces. A: Physicochem. Eng. Aspects 228 (2003) 143-158
J. Laine, P. Stenius, G. Carlsson and G. Ström, The effect of elemental chlorine-free (ECF) and totally chlorine-free (TCF) bleaching on the surface chemical composition of kraft pulp as determined by ESCA. Nordic Pulp Paper Res. J. 11 (1996) 201-210
W. Shen and I.H. Parker, Surface composition and surface energetics of various eucalypt pulps. Cellulose 6 (1999) 41-55
E. Sjöström and B. Enström, A method for separate determination of sulfo and carboxyl groups in sulfite pulps. Svensk Papperstidning 69 (1966) 55-59
E. Sjöström and P. Haglund, Factors affecting the determination of carboxyl groups in cellulose. Svensk Papperstidning 64 (1961) 438-446
Stenius P. and Vuorinen, T. 1998. Direct characterization of chemical properties of fibers. In: Sjöström E. and Alen R.(eds) Analytical Methods in Wood Chemistry, Pulping, and Papermaking. SpringerBerlin, Germany, pp. 149–192.
G. Ström and G. Carlsson, Wettability of kraft pulps - effect of surface composition and oxygen plasma treatment. J. Adhesion Sci. Technol. 6 (1992) 745-761
Y. Sumi, R.D. Hale, J.A. Meyer, B. Leopold and B.G. Ranby, Accessibility of wood and wood carbohydrates measured with tritiated water. Tappi 47 (1964) 621-624
S. Tasker, J.P.S. Badyal, S.C.E. Backson and R.W. Richards, Hydroxyl accessibility in celluloses. Polymer 35 (1994) 4717-4721
Toriz, G., Denes F. and Young R.A. 2000. Plasma Modification of Lignin. In: Glasser W.G., Northey R.A. and Schultz T.P.(eds), Lignin: Historical, Biological, and Materials Perspectives. ACS Symposium Series, vol. 742, pp. 367–389.
G. Toriz, J. Ramos and R.A. Young, Lignin-polypropylene composites Part II. Plasma modification of kraft lignin and particulate polypropylene. J. Appl. Polym. Sci. 91 (2004) 1920-1926
L. Wågberg, L. Winter and T. Lindström, Papermaking Raw Materials. London: Mechanical Engineering Ltd (1985).
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Östenson, M., Järund, H., Toriz, G. et al. Determination of Surface Functional Groups in Lignocellulosic Materials by Chemical Derivatization and ESCA Analysis. Cellulose 13, 157–170 (2006). https://doi.org/10.1007/s10570-005-5855-z
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DOI: https://doi.org/10.1007/s10570-005-5855-z