Engineered Superparamagnetic Core–Shell Metal–Organic Frame-Work (Fe3O4@Ni–Co-BTC NPs) with Enhanced Photocatalytic Activity for Selective Aerobic Oxidation of Alcohols Under Solar Light Irradiation

Catalysis Letters volume 151, pages107–123(2021)Cite this article

Abstract

This paper reported an environmentally benign strategy for the synthesis of a magnetic metal–organic framework (Fe3O4@Ni–Co-BTCNPs) via a multi-step procedure. The catalytic performance of Fe3O4@Ni–Co-BTCNPs was evaluated in the selective aerobic oxidation of alcohol substrates (including primary and secondary aliphatic and benzylic alcohols) in water and under solar light irradiation.

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Acknowledgements

The authors gratefully acknowledge the partial support of this study by Ferdowsi University of Mashhad Research Council (Grant No. p/3/43367).

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  1. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, 9177948974, Iran

    Arezou Mohammadinezhad & Batool Akhlaghinia

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  1. Arezou Mohammadinezhad
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Correspondence to Batool Akhlaghinia.

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Mohammadinezhad, A., Akhlaghinia, B. Engineered Superparamagnetic Core–Shell Metal–Organic Frame-Work (Fe3O4@Ni–Co-BTC NPs) with Enhanced Photocatalytic Activity for Selective Aerobic Oxidation of Alcohols Under Solar Light Irradiation. Catal Lett 151, 107–123 (2021). https://doi.org/10.1007/s10562-020-03291-z

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Keywords

  • Magnetic metal–organic framework (Fe3O4@Ni–Co-BTCNPs)
  • Green media
  • Solar light irradiation