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Preparation and Characterization of an Efficient Nano-Inorganic Composite of CuO/ZnO/Al2O3 for the Catalytic Amination of Aryl Halides in Aqueous Conditions

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Abstract

In this research, an efficient recyclable nano-inorganic composite of CuO/ZnO/Al2O3 (CuO/ZnO/Al2O3 nanocatalyst) is prepared, characterized and used for the amination of aryl halides with aqueous ammonia in water. The catalyst was prepared by co-precipitation method and characterized by various techniques such as the X-ray diffraction, scanning electron microscope, energy dispersive spectroscopy, and brunauer–Emmett–Teller surface area analysis. Various aryl halides reacted with aqueous ammonia and corresponding products were obtained in high yields. CuO/ZnO/Al2O3 nanocatalyst as an efficient stable catalyst is recyclable up to five consecutive runs by simple filtration.

Graphical Abstract

An efficient recyclable nano-inorganic composite of CuO/ZnO/Al2O3 (CuO/ZnO-Al2O3 nanocatalyst) is prepared, characterized and used for the amination of aryl halides with aqueous ammonia in water.

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Acknowledgements

We are grateful to the research council of Shahrekord university, for the support of this research.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Shahrekord University, Shahrekord, Iran

    Jalal albadi & Heshmat Allah Samimi

  2. National Petrochemical Company, Petrochemical Research and Technology Company, Tehran, Iran

    Mehdi Jalali

Authors
  1. Jalal albadi
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  2. Mehdi Jalali
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  3. Heshmat Allah Samimi
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Correspondence to Jalal albadi.

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albadi, J., Jalali, M. & Samimi, H.A. Preparation and Characterization of an Efficient Nano-Inorganic Composite of CuO/ZnO/Al2O3 for the Catalytic Amination of Aryl Halides in Aqueous Conditions. Catal Lett 148, 3750–3756 (2018). https://doi.org/10.1007/s10562-018-2567-1

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  • DOI: https://doi.org/10.1007/s10562-018-2567-1

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