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Catalysis Letters

, Volume 148, Issue 6, pp 1676–1685 | Cite as

Visible-Light-Mediated Synthesis of 4H-benzo[1,4]thiazin-2-amines and 3,4-Dihydroquinoxalin-2-amines: An Efficient and Metal Free Route to C–S, C–N Bond Formation

  • Neetu Yadav
  • Hozeyfa Sagir
  • Mohd. Danish Ansari
  • I. R. Siddiqui
Article

Abstract

An efficient and practical synthesis of benzothiazine by visible-light-mediated free radical reaction has been developed. This protocol provides a new, facile, eco-friendly strategy to construct benzothiazine and quinoxaline derivatives via formation of C–S and C–N bonds under metal-free condition. This synthesis has been performed under visible light illumination in aqueous ethanol at room temperature using aromatic aldehyde, o-aminothiophenol and isocyanide as reactants.

Graphical Abstract

Keywords

Visible-light Metal-free Eco-sustainable Benzo[1,4]thiazin-2-amine 

Notes

Acknowledgements

The authors gratefully acknowledge SAIF, Punjab University Chandigarh for providing all the spectroscopic and analytical data. N. Yadav is grateful to CSIR, New Delhi for the award of Junior Research Fellowship, H. Sagir to UGC, New Delhi for the award of Senior Research Fellowship (SRF) and D. Ansari acknowledge UPCST for the financial support.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Neetu Yadav
    • 1
    • 2
  • Hozeyfa Sagir
    • 1
    • 2
  • Mohd. Danish Ansari
    • 1
    • 2
  • I. R. Siddiqui
    • 1
    • 2
  1. 1.Department of ChemistryUniversity of AllahabadAllahabadIndia
  2. 2.Laboratory of Green Synthesis, Department of ChemistryUniversity of AllahabadAllahabadIndia

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