Catalysis Letters

, Volume 148, Issue 6, pp 1692–1702 | Cite as

KCC-1 Supported Ruthenium-Salen-Bridged Ionic Networks as a Reusable Catalyst for the Cycloaddition of Propargylic Amines and CO2

  • Seyed Mahdi Saadati
  • Seyed Mohsen Sadeghzadeh


This study investigates the potential application of an efficient, easily recoverable and reusable KCC-1 nanoparticle-supported Salen/Ru(II) catalyst in the synthesis of 2-oxazolidinones from CO2, and propargylic amines. The KCC-1/Salen/Ru(II) NPs were thoroughly characterized by using TEM, SEM, TGA, FT-IR, ICP-MS, and BET. This observation was exploited in the direct and selective chemical fixation of CO2, affording high degrees of CO2 capture and conversion. The recycled catalyst has been analyzed by ICP-MS showing only minor changes in the morphology after the reaction, thus confirming the robustness of the catalyst.

Graphical Abstract


Nano catalyst KCC-1 One-pot synthesis Green chemistry CO2 



The authors gratefully acknowledge the financial support of Islamic Azad University, Bojnourd Branch, Bojnourd, Iran.


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Seyed Mahdi Saadati
    • 1
  • Seyed Mohsen Sadeghzadeh
    • 2
  1. 1.Department of Chemistry, Bojnourd BranchIslamic Azad UniversityBojnourdIran
  2. 2.Young Researchers and Elite Club, Neyshabur BranchIslamic Azad universityNeyshaburIran

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