A Study of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol Over Pt–WOx/C

  • Cong Wang
  • Jennifer D. Lee
  • Yichen Ji
  • Tzia Ming Onn
  • Jing Luo
  • Christopher B. Murray
  • Raymond J. Gorte
Article
  • 18 Downloads

Abstract

The hydrogenolysis of tetrahydrofurfural alcohol to 1,5-pentanediol was studied over a series of carbon-supported metal/metal-oxide pairs. In agreement with previous reports, specific pairs, especially Pt and Ir paired with WOx, MoOx and ReOx, exhibited high activity and selectivity, even though the individual components were not active or selective. Only reducible oxides produced selective catalysts. A more comprehensive study of the Pt–WOx system indicated that the active form of the catalyst exists as a thin, submonolayer film of the oxide on the Pt surface. This film could be formed by atomic layer deposition (ALD) of W(CO)6 onto the Pt nanocrystals and STEM–EDS mapping demonstrated that ALD deposition occurred selectively on the Pt. When the catalyst was formed by impregnation of Pt and W salts, the WOx was mobile and able to move onto the Pt. The implications of these result for preparing selective catalysts are discussed.

Graphical Abstract

Keywords

Hydrogenolysis Tetrahydrofurfuryl alcohol 1,5-Pentanediol Pt–WOx/C Atomic layer deposition 

Notes

Acknowledgements

We acknowledge support from the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award no. DE-SC0001004. J.D.L acknowledge the support from the U.S. Department of Energy, Office of Science, Office of Workforce Development for Teachers and Scientists, Office of Science Graduate Student Research (SCGSR) program. The SCGSR program is administered by the Oak Ridge Institute for Science and Education (ORISE) for the DOE. ORISE is managed by ORAU under Contract Number DE-SC0014664.

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no financial or other conflicts of interest regarding this work.

Supplementary material

10562_2018_2323_MOESM1_ESM.docx (4.3 mb)
Supplementary material 1 (DOCX 4390 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Cong Wang
    • 1
  • Jennifer D. Lee
    • 2
  • Yichen Ji
    • 1
  • Tzia Ming Onn
    • 1
  • Jing Luo
    • 1
  • Christopher B. Murray
    • 2
    • 3
  • Raymond J. Gorte
    • 1
    • 3
  1. 1.Department of Chemical & Biomolecular EngineeringUniversity of PennsylvaniaPhiladelphiaUSA
  2. 2.Department of ChemistryUniversity of PennsylvaniaPhiladelphiaUSA
  3. 3.Department of Materials Science and EngineeringUniversity of PennsylvaniaPhiladelphiaUSA

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