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2,6-Bis(2-methylhydrazine-1-carbonyl)pyridine 1-oxide as an Efficient Ligand for Copper-Catalyzed C–N Coupling Reaction in Water

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Abstract

Cu2O/2,6-bis(2-methylhydrazine-1-carbonyl)pyridine 1-oxide was found to be an efficiently catalytic system for the N-arylation of imidazole, indole, benzimidazole, pyrrole, benzylamine and ethanolamine with aryl iodides and bromides by using NaOH as base in the presence of 20 mol% (n-Bu)4NBr, and water as solvent at 130 °C in 24 h, and giving the N-arylated products in moderate to excellent yields.

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Acknowledgements

We gratefully acknowledge the Natural Science Foundation of China (21606153) for the financial support.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi, 832003, China

    Xiaochuang Wang, Jie Zhang, Jianwei Xie & Bin Dai

  2. Guangdong Bioengineering Institute, Guangdong Academy of Science, Guangzhou, 510316, China

    Fei Meng

Authors
  1. Xiaochuang Wang
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  2. Fei Meng
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  3. Jie Zhang
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  4. Jianwei Xie
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  5. Bin Dai
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Corresponding author

Correspondence to Jianwei Xie.

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Wang, X., Meng, F., Zhang, J. et al. 2,6-Bis(2-methylhydrazine-1-carbonyl)pyridine 1-oxide as an Efficient Ligand for Copper-Catalyzed C–N Coupling Reaction in Water. Catal Lett 148, 1142–1149 (2018). https://doi.org/10.1007/s10562-018-2321-8

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  • DOI: https://doi.org/10.1007/s10562-018-2321-8

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