Kinetic and Mechanisms of the Aqueous-Biphasic Hydroformylation of Olefins Contained in Naphtha Cuts Catalyzed by RhH(CO)(TPPTS)3 [TPPTS: Tri(sodium m-sulfonated-phenyl)phosphine]
A kinetic study of the individual olefins present in naphtha, their mixture (synthetic naphtha) and the olefins present in a real naphtha was carried out using RhH(CO)(TPPTS)3 [TPPTS: tri(sodium m-sulfonated-phenyl)phosphine] as the catalyst precursor in aqueous-biphasic medium (toluene/water or naphtha/water), under mild reaction conditions: 80 °C, 800 psi (55.4 atm) and 600 rpm. The study consisted in the characterization of real naphtha, the selection of the model olefins, the preparation of synthetic naphtha, followed by hydroformylation of the individual olefins, of the olefin mixture and of a real naphtha cut. For 1-hexene aqueous-biphasic reaction, a kinetic study based on initial rate method showed a first order dependence on catalyst, substrate and dissolved hydrogen concentrations, whereas a fractional order was observed for carbon monoxide concentration. This kinetic results are in accord with the traditional hydroformylation mechanism, the hydrogenolysis of rhodium-acyl species being the rate-determining step of the cycle. From all the reaction profiles, it was corroborated by using the integral method that the dependence with respect to the olefin concentration was of first order for the aqueous-biphasic hydroformylation of individual olefins and their mixture, as well as for the olefins present in real naphtha cut. These results are important because of knowing the kinetics and mechanisms of the hydroformylation of the olefins present in naphtha, it is possible to improve the activity of the precatalyst and/or to design new ones for this type of application, i.e. the improving of the fuel quality through the green technology of aqueous-biphasic catalysis.
KeywordsAqueous-biphasic hydroformylation Olefins Naphtha Rhodium Kinetics
We thank FONACIT (Caracas) for financial support through the Project F-97003766, CONIPET Project 97-003777 and CODECIH-UC Project 94017. We are thankful to Red Iberoamericana de Ciencia y Tecnología Para el Desarrollo, CYTED, Project V.9 and the Universidad de Carabobo for permitting the publication of this work.
- 1.Bhaduri S, Mukesh D (2014) Homogeneous catalysis: mechanisms and industrial applications. Wiley, Nueva York, pp 141–150Google Scholar
- 4.California Air Resources Board, The California Reformulated Gasoline Regulations, Title 13, California Code of Regulations., Sect 2250-2273.5 Reflecting Amendments Effective August 29, 2008Google Scholar
- 5.American Society for Testing and Materials (ASTM): ASTM D6550-15 (2015) Standard test method for determination of olefin content of gasoline by supercitical-fluid chromatography. http://www.astm.org/Standards/D6550.htm. Accessed 6 Oct 2017
- 6.Joó F (2001) Aqueous organometallic catalysis. In: James B, van Leeuwen PWNM (ed) Catalysis by metal complexes. Kluwer Academic Publishers, DordrechtGoogle Scholar
- 11.Melean LG, Rivera S, Guanipa VJ, Modroño-Alonso M, Gonzalez A, Rosales M, Baricelli PJ (2011) Hydrocarb World 6:12–15Google Scholar
- 12.Rosales M, Baricelli PJ, González A (2012) Ciencia 20:73–85Google Scholar
- 13.Baricelli P, Melean LG, Modroño-Alonso M, Rodriguez A, Rosales M, González A (2014) Catal Today 247:124 131Google Scholar
- 18.Cavalieri d’Oro P, Raimondi L, Pagani G, Montrasi G, Gregorio G, Andreeta A, Chim (1982) Ind (Milan) 62:572Google Scholar
- 24.Van Leeuwen PCJ, Claver C (2000) Rhodium Catalyzed Hydroformylation. Kluwer Academic Publisher, DordrechtGoogle Scholar
- 28.Kurtz E (1987) Homogeneous catalysis in water. Chemtech 17:570–575Google Scholar