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Catalysis Letters

, Volume 148, Issue 2, pp 555–563 | Cite as

Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols

  • Cheng Liu
  • Wei Luo
  • Junhua Liu
  • Lei Sun
  • Yue Yang
  • Gui Liu
  • Fang Wang
  • Wei Zhong
  • Curtis Guild
  • Steven L. Suib
Article

Abstract

Four micro (nano)-sized mesoporous ferric hydroxyphosphates (FHP) are synthesized by a reverse microemulsion-solvothermal method, and then are used as supports to prepare supported Pt catalysts. The mean particle diameter of Pt nanoparticles (NPs) was 4.5–4.6 nm. When the four different Pt/FHP catalysts were used into the hydrogenation of α,β-unsaturated aldehydes (ketones) to their corresponding unsaturated alcohols, Pt/FHP (c) catalyst showed better catalytic performance than the other three partners. Under the optimal experimental conditions, several tested α,β-unsaturated aldehydes could be effectively transformed into corresponding unsaturated alcohols over Pt/FHP (c) catalyst. The catalyst could be recycled and reused several times without activity loss. We propose the stronger interaction between the Pt NPs and ferric ions of the FHP (c) are responsible for its good catalytic performance, and this stronger interaction should be rooted in its enhanced Lewis acid strength.

Graphical Abstract

Keywords

α,β-Unsaturated aldehydes (ketones) Ferric hydroxyphosphates Lewis acid Pt nanoparticles Selective hydrogenation 

Notes

Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (21703101, 21303085), the Natural Science Foundation of Jiangsu Province (BK20130901, BK20130930), the Program to Cultivate Outstanding Young Key Teachers of Nanjing Normal University (Qinglan Project), Postgraduate Research & Practice Innovation Program of Jiangsu Province (KYCX17-1087) and the Priority Academic Program Development of Jiangsu Higher Education Institutions. SLS acknowledges the support of the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical, Biological and Geological Sciences under Grant DE-FG02-86ER13622.A000.

Supplementary material

10562_2017_2280_MOESM1_ESM.docx (166 kb)
Supplementary material 1 (DOCX 166 KB)

References

  1. 1.
    Bauer K, Garbe D (1985) Common fragrance and flavor materials. VCH, WeinheimGoogle Scholar
  2. 2.
    Berger RG (2007) Flavors and fragrance Ingredients. Springer, BerlinCrossRefGoogle Scholar
  3. 3.
    Lenz J, Campo BC, Alvarez M, Volpe MA (2009) J Catal 267:50CrossRefGoogle Scholar
  4. 4.
    Wu B, Huang H, Yang J, Zheng N, Fu G (2012) Angew Chem Int Ed 51:3440CrossRefGoogle Scholar
  5. 5.
    Bruyn M, De Coman S, Bota R, Parvulescu VI, De Vos DE, Jacobs PA (2003) Angew Chem Int Ed 42:5333CrossRefGoogle Scholar
  6. 6.
    Mercadante L, Neri G, Milone C, Donato A, Galvagno S (1996) J Mol Catal A Chem 105:93CrossRefGoogle Scholar
  7. 7.
    Melean LG, Rodriguez M, González A, González B, Rosales M, Baricelli PJ (2011) Catal Lett 141:709CrossRefGoogle Scholar
  8. 8.
    Prakash MG, Mahalakshmy R, Krishnamurthya KR, Viswanathan B (2015) Catal Sci Technol 5:3313CrossRefGoogle Scholar
  9. 9.
    Bhogeswararao S, Srinivas D (2012) J Catal 285:31CrossRefGoogle Scholar
  10. 10.
    Stassi JP, Zgolicz PD, Rodríguez VI, de Miguel SR, Scelza OA (2015) Appl Catal A Gen 497:58CrossRefGoogle Scholar
  11. 11.
    Stassi JP, Zgolicz PD, de Miguel SR, Scelza OA (2013) J Catal 306:11CrossRefGoogle Scholar
  12. 12.
    Mahata F, Gonçalves N, Pereira MFR, Figueiredo JL (2008) Appl Catal A Gen 339:159CrossRefGoogle Scholar
  13. 13.
    Liu J, Liu G, Liu C, Li W, Wang F (2016) Catal Sci Technol 6:2055CrossRefGoogle Scholar
  14. 14.
    Wu X, Song X, Li D, Liu J, Zhang P, Chen X (2012) J Bionic Eng 9:224CrossRefGoogle Scholar
  15. 15.
    Sing KSW (1982) Pure Appl Chem 54:2201CrossRefGoogle Scholar
  16. 16.
    Wu G, Chen Z, Artyushkova K, Garzon FH, Zelenay P (2008) ECS Trans 16:159CrossRefGoogle Scholar
  17. 17.
    Kendelewicz T, Liu P, Doyle CS, Brown GE Jr (2000) Surf Sci 469:144CrossRefGoogle Scholar
  18. 18.
    Hanks TW, Ekeland RA, Emerson K, Larsen RD, Jennings PW (1987) Organometallics 6:28CrossRefGoogle Scholar
  19. 19.
    de Miguel SR, Scelza OA, Román-Martínez MC, de Lecea CSM, Cazorla-Amorós D, Linares-Solano A (1998) Appl Catal A Gen 170:93CrossRefGoogle Scholar
  20. 20.
    Trasarti AF, Bertero NM, Apesteguía CR, Marchi AJ (2014) Appl Catal A Gen 475:282CrossRefGoogle Scholar
  21. 21.
    Bertero NM, Trasarti AF, Apesteguía CR, Marchi AJ (2011) Appl Catal A Gen 394:228CrossRefGoogle Scholar
  22. 22.
    Liu Z, Wang C, Liu Z, Lu J (2008) Appl Catal A Gen 344:114CrossRefGoogle Scholar
  23. 23.
    Zhou G, Pei Y, Jiang Z, Fan K, Qiao M, Sun B, Zong B (2014) J Catal 311:393CrossRefGoogle Scholar
  24. 24.
    Sun J, Zhu K, Gao F, Wang C, Liu J, Peden CHF, Wang Y (2011) J Am Chem Soc 133:11096CrossRefGoogle Scholar
  25. 25.
    Chang FW, Roselin LS, Ou TC (2008) Appl Catal A Gen 334:147CrossRefGoogle Scholar
  26. 26.
    Koch AJH, Koch M, Fortuin HM, Geos JW (1985) J Catal 96:261CrossRefGoogle Scholar
  27. 27.
    Lin R, Ding Y, Wang R (2014) J Energy Chem 23:29CrossRefGoogle Scholar
  28. 28.
    Yu C, Ge Q, Xu H, Li W (2006) Appl Catal A Gen 315:58CrossRefGoogle Scholar
  29. 29.
    Ge X, Li M, Shen J (2001) J Solid State Chem 161:38CrossRefGoogle Scholar
  30. 30.
    Ji Y, Zhao Z, Duan A, Jiang G. Liu J (2009) J Phys Chem C 113:7186CrossRefGoogle Scholar
  31. 31.
    Sankaranarayanan TM, Berenguer A, Ochoa-Hernándeza C, Moreno I, Jana P, Coronado JM, Serranoa DP, Pizarro P (2015) Catal Today 243:163CrossRefGoogle Scholar
  32. 32.
    Tang H, Wei J, Liu F, Qiao B, Pan X, Li L, Liu J, Wang J, Zhang T (2016) J Am Chem Soc 138:56CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • Cheng Liu
    • 1
  • Wei Luo
    • 1
  • Junhua Liu
    • 1
  • Lei Sun
    • 1
  • Yue Yang
    • 1
  • Gui Liu
    • 1
  • Fang Wang
    • 2
  • Wei Zhong
    • 3
  • Curtis Guild
    • 3
  • Steven L. Suib
    • 3
  1. 1.College of Chemistry and Materials ScienceNanjing Normal UniversityNanjingChina
  2. 2.College of Chemistry and Molecular EngineeringNanjing Tech UniversityNanjingChina
  3. 3.Department of ChemistryUniversity of ConnecticutStorrsUSA

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