Catalysis Letters

, Volume 148, Issue 2, pp 512–522 | Cite as

Synthesis of Co/Al2O3 Catalysts and Their Application in Heptane Steam Reforming

  • Elizaveta A. Dorofeeva
  • Arkady Yu. Postnov
  • Elena A. Pavlova
  • Evgeniy A. Vlasov
  • Markus Peurla
  • Päivi Mäki-Arvela
  • Dmitry Yu. Murzin
Article
  • 84 Downloads

Abstract

Synthesis of multi-component cobalt based catalysts with different metal precursors and thermal treatment was performed. A special emphasis was put on promotion with ceria. Catalysts, which were synthesized from thermally pre-activated CoCO3·mCo(OH)2·nH2O as a precursor and thereafter underwent reduction in flowing hydrogen, have a clear tendency for decomposition of mixed aluminum–cobalt containing complexes, inevitably formed during thermal treatment. The catalysts were tested in steam reforming of hydrocarbons. The size of metal particles in reduced catalysts was determined by TEM and related to catalytic activity.

Graphical Abstract

Keywords

Cobalt catalysts Catalyst preparation Heptane steam reforming 

Notes

Acknowledgements

Research work is performed within a grant of the Government of the Russian Federation for the state support of the scientific researchers conducted under the leadership of the leading scientists.

Supplementary material

10562_2017_2256_MOESM1_ESM.docx (698 kb)
Supplementary material 1 (DOCX 698 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • Elizaveta A. Dorofeeva
    • 1
  • Arkady Yu. Postnov
    • 1
  • Elena A. Pavlova
    • 1
  • Evgeniy A. Vlasov
    • 1
  • Markus Peurla
    • 2
  • Päivi Mäki-Arvela
    • 3
  • Dmitry Yu. Murzin
    • 3
  1. 1.St. Petersburg State Institute of Technology (Technical University)St. PetersburgRussia
  2. 2.University of TurkuTurkuFinland
  3. 3.Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry CentreAbo Akademi UniversityTurkuFinland

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