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Study on the Liquid Phase Oxidation of p-Tert-butyltoluene Over Ni/NaY

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An Author Correction to this article was published on 10 March 2018

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Abstract

Metal-modified molecular sieves (MNaY, M = Ni, Co, Cu) have been synthesized by the impregnation method, these catalysts were used for the study of liquid phase oxidation of p-tert-butyltoluene (PTBT) to synthesize p-tert-butylbenzaldehyde (PTBD) for the first time. The catalysts have been characterized by X-ray, XPS, SEM, BET, and TGA. The results show that the Ni/NaY exhibits suitable and stable catalytic activity. Recycle runs show that Ni/NaY was stable for at least five cycles. Under the optimized conditions of having a reaction time of 7 h, 6 mL of PTBT, 0.2 g of Ni/NaY, 0.1 g of N-hydroxyphthalimide (NHPI), 18 mL of acetonitrile, a reaction temperature of 70 °C, and a rotating speed 200 r/min, the conversion of PTBT reached 29.3–30.6% with a PTBD selectivity of 77.2%.

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  • 10 March 2018

    In the original version of this article, the corresponding author information was incorrect. This has been corrected with this erratum. The correct corresponding author is Dr. Jiang-Quan Ma.

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Acknowledgements

This work was financially supported by Industry Supporting Project of Zhenjiang of Jiangsu Province (GY2014037); and Industry Supporting Project of Changzhou of Jiangsu Province (CE20140077).

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Authors and Affiliations

  1. Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Gehu Road 1, Changzhou, 213164, Jiangsu, People’s Republic of China

    Qian Yin, Ting-Ting Shen, Jiang-Quan Ma, Jia Yan, Jun Xu & Xue-Mei Tian

Authors
  1. Qian Yin
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  2. Ting-Ting Shen
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  3. Jiang-Quan Ma
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  4. Jia Yan
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  5. Jun Xu
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Corresponding author

Correspondence to Qian Yin.

Additional information

(1)NaY molecular sieve: industrial products (Liaoning Haitai Technology Development Co., Ltd.); (2)cobalt acetate: AR (Shanghai Maike Lin Biochemical Technology Co., Ltd.); (3)nickel nitrate, copper nitrate: AR (MeiLan Industrial Shanghai Co., Ltd.); (4)P-tert-butyl toluene: industrial products (Jiangsu Lvyuan Fine Chemical Co., Ltd.); (5)N-hydroxy phthalimide (NHPI): 98% for research and development (Beijing Braunway Technology Co., Ltd.); (6)acetonitrile: AR (Shanghai Mai Ruier Chemical Technology Co., Ltd. Company).

A correction to this article is available online at https://doi.org/10.1007/s10562-018-2344-1.

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Yin, Q., Shen, TT., Ma, JQ. et al. Study on the Liquid Phase Oxidation of p-Tert-butyltoluene Over Ni/NaY. Catal Lett 147, 1214–1220 (2017). https://doi.org/10.1007/s10562-017-2018-4

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  • DOI: https://doi.org/10.1007/s10562-017-2018-4

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