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Catalysis Letters

, Volume 146, Issue 10, pp 2032–2040 | Cite as

Fe/MMT as an Effective Catalyst for Furan Production from Eucalyptus Enzymatic Hydrolysate in Biphasic Systems

  • Weiqi Wei
  • Shubin Wu
Article

Abstract

Heterogeneous catalyst, Fe/MMT, was prepared by ion-exchanged and used for conversion the eucalyptus enzymatic hydrolysate into furan products. The result shown prepared Fe/MMT catalyst, having large specific surface area and high acid loading, containing both Lewis and Brønsted acid sites, displayed high activity and good stability during the dehydration reaction. The highest 5-HMF and furfural yields obtained from enzymatic hydrolysate are up to 70.21 and 78.84 %, respectively, a slight higher than those from pure sugar solution. Moreover, a reaction pathway for conversion of C6 and C5 sugar that in the hydrolysate into furan products in the present of Fe/MMT catalyst were also proposed in this study.

Graphical Abstract

Keywords

Eucalyptus enzymatic hydrolysate Fe/MMT catalyst Catalytic conversion Furan products 

Notes

Acknowledgments

The authors greatly acknowledge the support of Science and Technology Project of Guangzhou City (No. 201607020025), National Basic Research Program of China (No. 2013CB228101), and State Key Laboratory of Pulp and Paper Engineering (No. 2014T05).

References

  1. 1.
    Lange JP, Price R, Ayoub PM, Clarke L, Gosselink H (2010) Angew Chem Int Ed 49:4479CrossRefGoogle Scholar
  2. 2.
    Alonso DM, Wettstein SG, Mellmer MA, Gurbuz EI, Dumesic JA (2013) Energy Environ Sci 6:76CrossRefGoogle Scholar
  3. 3.
    Xiang X, He L, Yang Y, Guo B, Tong D, Hu C (2011) Catal Lett 141:735CrossRefGoogle Scholar
  4. 4.
    Karimi B, Mirzaei HM, Farhangi E (2014) ChemCatChem 6:758CrossRefGoogle Scholar
  5. 5.
    Qi XH, Watanabe M, Aida TM, Smith RL (2011) Cellulose 18:1327CrossRefGoogle Scholar
  6. 6.
    Yang Y, Hu CW, Abu-Omar MM (2012) ChemSusChem 5:405CrossRefGoogle Scholar
  7. 7.
    Choudhary V, Mushrif SH, Ho C, Anderko A, Nikolakis V, Marinkovic NS, Frenkel AI, Sandler SI, Vlachos DG (2013) J Am Chem Soc 135:3997CrossRefGoogle Scholar
  8. 8.
    Enslow KR, Bell AT (2015) Catal Sci Technol 5:2839CrossRefGoogle Scholar
  9. 9.
    Shen Y, Xu YF, Sun JK, Wang B, Xu F, Sun RC (2014) Catal Commun 50:17CrossRefGoogle Scholar
  10. 10.
    Jiménez-Morales I, Moreno-Recio M, Santamaría-González J, Maireles-Torres P, Jiménez-López A (2015) Appl Catal B 164:70CrossRefGoogle Scholar
  11. 11.
    Liu B, Ba C, Jin MM, Zhang ZH (2015) Ind Crop Prod 76:781CrossRefGoogle Scholar
  12. 12.
    Wang J, Masui Y, Onaka M (2010) Tetrahedron Lett 51:3300CrossRefGoogle Scholar
  13. 13.
    Masui Y, Wang J, Teramura K, Kogure T, Tanaka T, Onaka M (2014) Microporous Mesoporous Mater 198:129CrossRefGoogle Scholar
  14. 14.
    Li HL, Ren JL, Zhong LJ, Sun RC, Liang L (2015) Bioresour Technol 176:242CrossRefGoogle Scholar
  15. 15.
    Wang JJ, Ren JW, Liu XH, Xi JX, Xia QN, Zu YH, Lu GZ, Wang YQ (2012) Green Chem 14:2506CrossRefGoogle Scholar
  16. 16.
    Zhang LX, Yu HB, Wang P, Li Y (2014) Bioresour Technol 151:355CrossRefGoogle Scholar
  17. 17.
    Wu SB, Wei WQ, Liu LG (2011) J South China Univ Technol 39:1Google Scholar
  18. 18.
    Pedersen AT, Ringborg R, Grotkjær T, Pedersen S, Woodley JM (2015) Chem Eng J 273:455CrossRefGoogle Scholar
  19. 19.
    Wei WQ, Wu SB, Liu LG (2012) Bioresour Technol 110:302CrossRefGoogle Scholar
  20. 20.
    Wei WQ, Wu SB, Liu LG (2013) Bioresour Technol 128:725CrossRefGoogle Scholar
  21. 21.
    Li HL, Chen XF, Ren JL, Deng H, Peng F, Sun RC (2015) Biotechnol Biofuels 8:127CrossRefGoogle Scholar
  22. 22.
    García-Sancho C, Agirrezabal-Telleria I, Güemez MB, Maireles-Torres P (2014) Appl Catal B 152:1CrossRefGoogle Scholar
  23. 23.
    Ding D, Wang J, Xi J, Liu X, Lu G, Wang Y (2014) Green Chem 16:3846CrossRefGoogle Scholar
  24. 24.
    Nie G, Tong X, Zhang Y, Xue S (2014) Catal Lett 144:1759CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.State Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouChina

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