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Microscope Analysis of Au–Pd/TiO2 Glycerol Oxidation Catalysts Prepared by Deposition–Precipitation Method

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Abstract

Gold–palladium bimetallic nanoparticle catalysts prepared by a deposition–precipitation method were effective for aerobic oxidation of glycerol to carboxylic acids. The role of palladium was to suppress C–C bond cleavage that is responsible for the formation of C2 by-product molecules. The nanoparticles were observed by microscope techniques, which further enabled characterizing the respective locations of Au and Pd within the particles.

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References

  1. Hutchings GJ (1985) J Catal 96:292–295

    Article  CAS  Google Scholar 

  2. Haruta M, Kobayashi T, Sano H, Yamada N (1987) ChemLett 16(2):405–408

    Google Scholar 

  3. Web site of Haruta Gold Inc. http://www.haruta-gold.com/en/products/

  4. Lopez-Sanchez JA, Dimitratos N, Miedziak P, Ntainjua E, Edwards JK, Morgan D, Carley AF, Tiruvalam R, Kiely CJ, Hutchings GJ (2008) Phys Chem Chem Phys 10(14):1921–1930

    Article  CAS  Google Scholar 

  5. Sandoval A, Aguilar A, Louis C, Traverse A, Zanella R (2011) J Catal 281(1):40–49

    Article  CAS  Google Scholar 

  6. Ajaikumar S, Ahlkvist J, Larsson W, Shchukarev A, Leino AR, Kordas K, Mikkola JP (2011) Appl Catal A 392(1–2):11–18

    Article  CAS  Google Scholar 

  7. Pagliaro M, Ciriminna R, Kimura H, Rossi M, Della Pina C (2007) Angew Chem Int Ed 46(24):4434–4440

    Article  CAS  Google Scholar 

  8. Pagliaro M, Rossi M (2010) In: The future of glycerol 2nd edn, RSC Green Chemistry Book Series. University of York, York

  9. Katryniok B, Kimura H, Skrzynska E, Girardon J-S, Fongarland P, Capron M, Ducoulombier R, Mimura N, Paul S, Dumeignil F (2011) Green Chem 13(8):1960–1979

    Article  CAS  Google Scholar 

  10. Kimura H, Tsuto K, Wakisaka T, Kazumi Y, Inaya Y (1993) Appl Catal 96(2):217–228

    Article  CAS  Google Scholar 

  11. Kimura H (1993) Appl Catal 105(2):147–158

    Article  CAS  Google Scholar 

  12. Bianchi CL, Canton P, Dimitratos N, Porta F, Prati L (2005) Catal Today 102–103:203–212

    Article  Google Scholar 

  13. Dimitratos N, Porta F, Prati L (2005) Appl Catal A 291(1–2):210–214

    Article  CAS  Google Scholar 

  14. Dimitratos N, Lopez-Sanchez JA, Anthonykutty JM, Brett G, Carley AF, Tiruvalam RC, Herzing AA, Kiely CJ, Knight DW, Hutchings GJ (2009) Phys Chem Chem Phys 11(25):4952–4961

    Article  CAS  Google Scholar 

  15. Dimitratos N, Villa A, Prati L (2009) Catal Lett 133(3–4):334–340

    Article  CAS  Google Scholar 

  16. Brett GL, He Q, Hammond C, Miedziak PJ, Dimitratos N, Sankar M, Herzing AA, Conte M, Lopez-Sanchez JA, Kiely CJ, Knight DW, Taylor SH, Hutchings GJ (2011) Angew Chem Int Ed 50(43):10136–10139

    Article  CAS  Google Scholar 

  17. Kondrat SA, Miedziak PJ, Douthwaite M, Brett GL, Davies TE, Morgan DJ, Edwards JK, Knight DW, Kiely CJ, Taylor SH, Hutchings GJ (2014) Chem Sus Chem 7(5):1326–1334

    Article  CAS  Google Scholar 

  18. Ketchie WC, Murayama M, Davis RJ (2007) J Catal 250(2):264–273

    Article  CAS  Google Scholar 

  19. Mimura N, Hiyoshi N, Fujitani T, Dumeignil F (2014) RSC Adv 4(63):33416–33423

    Article  CAS  Google Scholar 

  20. Haruta M, Tsubota S, Kobayashi T, Kageyama H, Genet MJ, Delmon B (1993) J Catal 144(1):175–192

    Article  CAS  Google Scholar 

  21. Ketchie W, Murayama M, Davis R (2007) Top Catal 44(1–2):307–317

    Article  CAS  Google Scholar 

  22. Skrzyńska E, Ftouni J, Mamede A-S, Addad A, Trentesaux M, Girardon J-S, Capron M, Dumeignil F (2014) J Mol Catal A 382:71–78

    Article  Google Scholar 

  23. Skrzyńska E, Wondołowska-Grabowska A, Capron M, Dumeignil F (2014) Appl Catal A 482:245–257

    Article  Google Scholar 

  24. Skrzyńska E, Ftouni J, Girardon J-S, Capron M, Jalowiecki-Duhamel L, Paul J-F, Dumeignil F (2012) Chem Sus Chem 5(10):2065–2078

    Article  Google Scholar 

  25. Shen Y, Zhang S, Li H, Ren Y, Liu H (2010) Chem Eur J 16(25):7368–7371

    Article  CAS  Google Scholar 

Download references

Acknowledgments

A part of this work was supported by Japan Society for the Promotion of Science (JSPS) KAKENHI Grant Number 25340130 and by the International Research Group ‘ECSAW’ (Environmental Catalysis for Sustaining Clean Air and Water) between CNRS and AIST.

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Authors and Affiliations

  1. Research Center for Compact Chemical System, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino-ku, Sendai, Miyagi, 983-8551, Japan

    Naoki Mimura & Norihito Hiyoshi

  2. Research and Innovation Promotion Headquarters, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki, 305-8568, Japan

    Masakazu Daté

  3. Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan

    Tadahiro Fujitani

  4. Unité de Catalyse et Chimie du Solide, UCCS, UMR CNRS 8181, Université Lille 1 Sciences et Technologies, 59655, Villeneuve d’Ascq, France

    Franck Dumeignil

  5. Institut Universitaire de France, Maison des Universités, 106 Boulevard Saint-Michel, 75005, Paris, France

    Franck Dumeignil

Authors
  1. Naoki Mimura
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  2. Norihito Hiyoshi
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  3. Masakazu Daté
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  4. Tadahiro Fujitani
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  5. Franck Dumeignil
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Corresponding authors

Correspondence to Naoki Mimura or Franck Dumeignil.

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Mimura, N., Hiyoshi, N., Daté, M. et al. Microscope Analysis of Au–Pd/TiO2 Glycerol Oxidation Catalysts Prepared by Deposition–Precipitation Method. Catal Lett 144, 2167–2175 (2014). https://doi.org/10.1007/s10562-014-1382-6

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  • DOI: https://doi.org/10.1007/s10562-014-1382-6

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