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Vanadium Mesoporous Silica Catalyst Prepared by Direct Synthesis as High Performing Catalyst in Oxidative Dehydrogenation of n-Butane

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Abstract

The catalytic oxidative dehydrogenation (ODH) of light alkanes has great potential to be used for production of alkenes instead classically used dehydrogenation. We report successful direct synthesis of vanadium mesoporous silica material—nSi/nV = 10 which could be convenient catalyst for ODH of alkane. The extraordinary high productivity (1.92 kgprod kg −1cat  h−1) in n-butane ODH is 3–4 times higher in comparison to supported vanadium catalysts usually prepared by wet impregnation method. It ranks this catalyst among the best materials investigated so far in this reaction. Moreover, reported catalytic system exhibits catalytic activity stable for more than 8 h in the stream.

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Acknowledgments

The authors thank to the project of the Czech Science Foundation No. P106/10/0196 for financial support.

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Authors and Affiliations

  1. Department of Physical Chemistry, University of Pardubice, Studentská 573, CZ532 10, Pardubice, Czech Republic

    Michal Setnička, Pavel Čičmanec & Roman Bulánek

  2. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 2155/3, CZ182 23, Prague 8, Czech Republic

    Arnošt Zukal & Jakub Pastva

Authors
  1. Michal Setnička
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  2. Pavel Čičmanec
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  3. Roman Bulánek
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  4. Arnošt Zukal
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  5. Jakub Pastva
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Correspondence to Michal Setnička.

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Setnička, M., Čičmanec, P., Bulánek, R. et al. Vanadium Mesoporous Silica Catalyst Prepared by Direct Synthesis as High Performing Catalyst in Oxidative Dehydrogenation of n-Butane. Catal Lett 144, 50–55 (2014). https://doi.org/10.1007/s10562-013-1158-4

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  • DOI: https://doi.org/10.1007/s10562-013-1158-4

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