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Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative

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Abstract

H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction.

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Acknowledgments

The authors thank to CONICET, Agencia Nacional de Promoción Científica y Tecnológica (Argentina), Comisión de Investigaciones Científicas (CIC), and Universidad Nacional de La Plata for financial support. AGS, GPR, GTB and HJT are members of CONICET.

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Authors and Affiliations

  1. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco” (CINDECA), Departamento de Química, Facultad de Ciencias Exactas, UNLP-CCT-CONICET, Calles 47°N 257, B1900AJK, La Plata, Argentina

    Laura M. Sanchez, Ángel G. Sathicq & Gustavo P. Romanelli

  2. Departamento de Ingeniería Química, Facultad de Ingeniería, Universidad de Buenos Aires, Ciudad Universitaria, C1428BG, Buenos Aires, Argentina

    Graciela T. Baronetti

  3. Planta Piloto Multipropósito PlaPiMu, UNLP-CICPBA, Camino Centenario y 508, CP1987, Manuel B. Gonnet, Argentina

    Horacio J. Thomas

Authors
  1. Laura M. Sanchez
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  2. Ángel G. Sathicq
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  3. Graciela T. Baronetti
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  4. Horacio J. Thomas
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  5. Gustavo P. Romanelli
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Correspondence to Graciela T. Baronetti.

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Sanchez, L.M., Sathicq, Á.G., Baronetti, G.T. et al. Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative. Catal Lett 144, 172–180 (2014). https://doi.org/10.1007/s10562-013-1111-6

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  • DOI: https://doi.org/10.1007/s10562-013-1111-6

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