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Noble Metal Promoted CeO2–ZrO2-Supported Ni Catalysts for Liquid-Phase Hydrogenation of Cinnamaldehyde

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Abstract

Pd or Pt promoted CeO2–ZrO2-supported Ni catalysts exhibited superior catalytic activity to the hitherto known Ni catalysts for liquid-phase hydrogenation of cinnamaldehyde at moderate conditions. Under similar experimental conditions, the unpromoted catalyst was selective for hydrocinnamaldehyde product (C=C hydrogenation) whereas the promoted catalyst yielded 3-phenyl propanol (C=C and C=O hydrogenation product). Enhanced dispersion of Ni was the cause for higher activity of the promoted Ni catalysts.

Graphical Abstract

Ni/CeO2–ZrO2 promoted with Pd/Pt showed high catalytic activity for liquid phase hydrogenation of cinnamaldehyde. The activity of these catalysts is superior to the hitherto known Ni catalysts.

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Acknowledgments

S.B. acknowledges the Council of Scientific and Industrial Research, New Delhi for the award of Senior Research Fellowship.

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Authors and Affiliations

  1. Catalysis Division, CSIR-National Chemical Laboratory, Pune, 411 008, India

    S. Bhogeswararao & D. Srinivas

  2. Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500 607, India

    V. Pavan Kumar & K. V. R. Chary

Authors
  1. S. Bhogeswararao
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  2. V. Pavan Kumar
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  3. K. V. R. Chary
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  4. D. Srinivas
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Correspondence to D. Srinivas.

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Bhogeswararao, S., Pavan Kumar, V., Chary, K.V.R. et al. Noble Metal Promoted CeO2–ZrO2-Supported Ni Catalysts for Liquid-Phase Hydrogenation of Cinnamaldehyde. Catal Lett 143, 1266–1276 (2013). https://doi.org/10.1007/s10562-013-1064-9

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  • DOI: https://doi.org/10.1007/s10562-013-1064-9

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