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Polymer-Anchored Cu(II) Complex as an Efficient Catalyst for Selective and Mild Oxidation of Sulfides and Oxidative Bromination Reaction

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Abstract

A new polymer-anchored Cu(II) complex has been tested for the oxidation of sulfides and in oxidative bromination reaction with hydrogen peroxide as oxidant. Sulfides have been selectively oxidized to corresponding sulfoxides in excellent yields and in presence of KBr as bromine source, organic substrates have been selectively converted to mono bromo substituted compounds. The polymer-anchored Cu(II) catalyst could be easily recovered by simple filtration and reused more than six times without appreciable loss of its initial activity.

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Acknowledgments

We thank the Department of Material Science, Indian Association of Cultivation of Science, Kolkata, for providing the instrumental support. MI acknowledges DST, CSIR and UGC, New Delhi, India for funding. ASR acknowledges CSIR, New Delhi, for providing his senior research fellowship. We acknowledge DST, Govt of India, for funding the University of Kalyani under purse programme.

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Authors and Affiliations

  1. Department of Chemistry, University of Kalyani, Kalyani, Nadia, 741235, WB, India

    Sk. M. Islam, Anupam Singha Roy, Paramita Mondal, Noor Salam & Sumantra Paul

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  1. Sk. M. Islam
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  2. Anupam Singha Roy
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  3. Paramita Mondal
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  4. Noor Salam
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  5. Sumantra Paul
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Correspondence to Sk. M. Islam.

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Islam, S.M., Roy, A.S., Mondal, P. et al. Polymer-Anchored Cu(II) Complex as an Efficient Catalyst for Selective and Mild Oxidation of Sulfides and Oxidative Bromination Reaction. Catal Lett 143, 225–233 (2013). https://doi.org/10.1007/s10562-012-0942-x

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  • DOI: https://doi.org/10.1007/s10562-012-0942-x

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