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Catalysis Letters

, Volume 142, Issue 5, pp 627–636 | Cite as

Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst

  • Mei Wu
  • Lingjun Chou
  • Huanling Song
Article

Abstract

Nickel modified Titanium silicalite 1 (TS-1) catalysts provided an environmentally benign and effective method for butadiene epoxidation. Certain loading of modified Ni in our system significantly promoted TS-1 catalytic activity. The product vinyloxirane (VO) was obtained with high yield of 0.49 mol/L (theoretic equilibrium value 0.52 mol/L). The turnover number (TON, determined as the molar VO obtained per molar Ti atom) reached 1,140. Besides, the catalyst kept high activity during five runs of reusability test. XRD, N2 adsorption and desorption, TPR, XPS, FT-IR and DR UV–Vis were employed to characterize the specific Ni role to Ti-site in Ni/TS-1 catalysts.

Graphical Abstract

Titanium silicalite 1 (TS-1) modified with different nickel contents as catalysts for the epoxidation of butadiene (BD) with hydrogen peroxide (H2O2). Vinyloxirane (VO) was obtained with high yield TON
.

Keywords

Butadiene Epoxidation Vinyloxirane Titanium silicalite 1 Nickel 

Notes

Acknowledgments

The authors sincerely acknowledge the financial support of the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhouPeople’s Republic of China
  2. 2.Graduate School of Chinese Academy of SciencesBeijingPeople’s Republic of China

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