Catalysis Letters

, Volume 142, Issue 1, pp 118–123 | Cite as

Dynamic Behavior of Pd Species in an LaFe0.95Pd0.05O3 Perovskite



LaFe0.95Pd0.05O3 prepared by a sol–gel process was stable under reducing atmospheres up to 1,073 K. Under reducing atmospheres metallic palladium left the LaFeO3 lattice and ionic palladium was reversibly incorporated into the perovskite framework in oxidizing environments. The catalytic activity of LaFe0.95Pd0.05O3 was higher than that of LaFeO3.

Graphical Abstract

Open image in new window


Heterogeneous catalysis Perovskite LaFeO3 Pd doping CO oxidation 


  1. 1.
    Nishihata Y, Mizuki J, Akao T, Tanaka H, Uenishi M, Kimura M, Okamoto T, Hamada N (2002) Nature 418:164CrossRefGoogle Scholar
  2. 2.
    Tanaka H, Taniguchi M, Kajita N, Uenishi M, Tan I, Sato N, Narita K, Kimura M (2004) Top Catal 30/31:389CrossRefGoogle Scholar
  3. 3.
    Uenishi M, Tanaka H, Taniguchi M, Tan I, Nishihata Y, Mizuki J, Kobayashi T (2008) Catal Commun 9:311CrossRefGoogle Scholar
  4. 4.
    Matsumura D, Nishihata Y, Mizuki J, Taniguchi M, Uenishi M, Tanaka H (2010) J Appl Phys 107:124319CrossRefGoogle Scholar
  5. 5.
    Cimino S, Casaletto MP, Lisi L, Russo G (2007) Appl Catal A 327:238CrossRefGoogle Scholar
  6. 6.
    Sartipi S, Khodadadi AA, Mortazavi Y (2008) Appl Catal B 83:214CrossRefGoogle Scholar
  7. 7.
    Chiarello GL, Grunwaldt JD, Ferri D, Krumeich F, Oliva C, Forni L, Baiker A (2007) J Catal 252:127CrossRefGoogle Scholar
  8. 8.
    Twagirashema I, Engelmann-Pirez M, Frere M, Burylo L, Gengembre L, Dujardin C, Granger P (2007) Catal Today 119:100CrossRefGoogle Scholar
  9. 9.
    Singh UG, Li J, Bennett JW, Rappe AM, Seshadri R, Scott SL (2007) J Catal 249:349CrossRefGoogle Scholar
  10. 10.
    Li J, Singh UG, Schladt TD, Stalick JK, Scott SL, Seshadri R (2008) Chem Mater 20:6567CrossRefGoogle Scholar
  11. 11.
    Ziaei-Azad H, Khodadadi A, Esmaeilnejad-Ahranjani P, Mortazavi Y (2011) Appl Catal B 102:62CrossRefGoogle Scholar
  12. 12.
    Cullity BD (1978) Elements of X-Ray Diffraction, 2nd edn. Addison-Wesley, Menlo ParkGoogle Scholar
  13. 13.
    Zhou KB, Chen HD, Tian Q, Hao ZP, Shen DX, Xu XB (2002) J Mol Catal A 189:225CrossRefGoogle Scholar
  14. 14.
    Zhang RD, Villanueva A, Alamdari H, Kaliaguine S (2006) J Catal 237:368CrossRefGoogle Scholar
  15. 15.
    Rossetti I, Forni L (2001) Appl Catal B 33:345CrossRefGoogle Scholar
  16. 16.
    Uenishia M, Taniguchi M, Tanaka H, Kimura M, Nishihata Y, Mizuki J, Kobayashi T (2005) Appl Catal B 57:267CrossRefGoogle Scholar
  17. 17.
    Ciambelli P, Cimino S, De Rossi S, Lisi L, Minelli G, Porta P, Russo G (2001) Appl Catal B 29:239CrossRefGoogle Scholar
  18. 18.
    Eyssler A, Mandaliev P, Winkler A, Hug P, Safonova O, Figi R, Weidenkaff A, Ferri D (2010) J Phys Chem C 114:4584CrossRefGoogle Scholar
  19. 19.
    Giraudon JM, Elhachimi A, Wyrwalski F, Siffert S, Aboukais A, Lamonier JF, Leclercq G (2007) Appl Catal B 75:157CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Xiaojing Zhang
    • 1
  • Huaju Li
    • 1
  • Yong Li
    • 1
  • Wenjie Shen
    • 1
  1. 1.State Key Laboratory of Catalysis, Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianChina

Personalised recommendations