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Catalysis Letters

, Volume 141, Issue 7, pp 958–967 | Cite as

Direct Hydrogenolysis of Highly Concentrated Glycerol Solutions Over Supported Ru, Pd and Pt Catalyst Systems

  • Esti van Ryneveld
  • Abdul S. Mahomed
  • Pieter S. van Heerden
  • Holger B. Friedrich
Article

Abstract

The evaluation of supported precious metal catalysts, in combination with and without solid acids, for the hydrogenolysis of highly concentrated glycerol solutions, with the aim to produce lower alcohols, in particular 1-propanol was studied. GCMS analysis of the product mixtures obtained has shed some light on the possible mechanism leading to unwanted condensation products, as well as the composition of these compounds.

Graphical Abstract

Keywords

Supported precious metal catalysts Solid acids Glycerol 1-propanol 

Notes

Acknowledgments

Thanks are due to Johnson & Matthey UK for the preparation of the precious metal catalysts and Sasol Technology for the support to perform this study.

References

  1. 1.
    Miyazawa T, Kusunoki Y, Kunimori K, Tomishige K (2006) J Catal 240:213CrossRefGoogle Scholar
  2. 2.
    Dasari MA, Kiatsimkul PP, Sutterlin WR, Suppes GJ (2005) Appl Catal A 281:225CrossRefGoogle Scholar
  3. 3.
    Tsukuda E, Sato S, Takahashi R, Sodesawa T (2007) Catal Comm 8:1349CrossRefGoogle Scholar
  4. 4.
    Hirai T, Ikenaga N, Miyake T, Suzuki T (2005) Energy Fuels 19:1761CrossRefGoogle Scholar
  5. 5.
    Furikado I, Miyazawa T, Koso S, Shimao A, Kunimori K, Tomishige K (2007) Green Chem 9:582CrossRefGoogle Scholar
  6. 6.
    Tanikella MSSR (1983) E.I. Du Pont de Nemours and Company. US Patent 4,404,411Google Scholar
  7. 7.
    Miyazawa T, Koso S, Kunimori K, Tomishige K (2007) Appl Catal A 329:30CrossRefGoogle Scholar
  8. 8.
    Miyazawa T, Kusunoki Y, Kunimori K, Tomishige K (2005) Catal Comm 6:645CrossRefGoogle Scholar
  9. 9.
    Balaraju M, Rekha V, Sai Prasad PS, Prabhavathi Devi BLA, Prasad RBN, Lingaiah N (2009) Appl Catal A 354:82CrossRefGoogle Scholar
  10. 10.
    Chaminand J, Djakovitch L, Gallezot P, Marion P, Pinel C, Rosier C (2004) Green Chem 6:359CrossRefGoogle Scholar
  11. 11.
    Ma L, He D, Li Z (2008) Catal Comm 9:2489CrossRefGoogle Scholar
  12. 12.
    Yuan Z, Wu P, Gao J, Lu X, Hou Z, Zheng X (2009) Catal Lett 130:261CrossRefGoogle Scholar
  13. 13.
    Feng J, Fu H, Wang J, Li R, Chen H, Li X (2008) Catal Comm 9:1458CrossRefGoogle Scholar
  14. 14.
    Shinmi Y, Koso S, Kubato T, Nakagawa Y, Tomishige K (2010) Appl Catal B 94:318CrossRefGoogle Scholar
  15. 15.
    Pavlechko PD (2009) Higher alcohols from syngas. SRI Consulting. PEP Report no. 268Google Scholar
  16. 16.
    Amada Y, Koso S, Nakagawa Y, Tomishige K (2010) ChemSusChem 3:728CrossRefGoogle Scholar
  17. 17.
    Lahr DG, Shanks BH (2005) J Catal 232:386CrossRefGoogle Scholar
  18. 18.
    Montassier C, Menezo JC, Hoang LC, Renaud C, Barbier J (1991) J Mol Catal 70:99CrossRefGoogle Scholar
  19. 19.
    Akiyama M, Sato S, Takahashi R, Inui K, Yokota M (2009) Appl Catal A 371:60CrossRefGoogle Scholar
  20. 20.
    Busca G (2007) Chem Rev 107:5366CrossRefGoogle Scholar
  21. 21.
    Santacesaria E, Grasso D (1990) Appl Catal 64:83CrossRefGoogle Scholar
  22. 22.
    Gandarias I, Arias PL, Requies J, Guemez MB, Fierro JLG (2010) Appl Catal B 97:248CrossRefGoogle Scholar
  23. 23.
    Deutsch J, Martin A, Lieske H (2007) J Catal 245:428CrossRefGoogle Scholar
  24. 24.
    Ruiz VR, Velty A, Santos LL, Leyva-Perez A, Sabater MJ, Iborra S, Corma A (2010) J Catal 271:351CrossRefGoogle Scholar
  25. 25.
    Patel SM, Chudasama UV, Ganeshpure PA (2003) J Mol Catal A 194:267CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Esti van Ryneveld
    • 1
  • Abdul S. Mahomed
    • 2
  • Pieter S. van Heerden
    • 2
  • Holger B. Friedrich
    • 1
  1. 1.School of ChemistryUniversity of KwaZulu-NatalDurbanSouth Africa
  2. 2.R&D DivisionSasol TechnologySasolburgSouth Africa

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