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Synthesis and Catalytic Abilities of Silica-coated Fe3O4 Nanoparticle Bonded Metalloporphyrins with Different Saturation Magnetization

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Abstract

In this paper, a series of nanoparticle bonded metalloporphyrins with different saturation magnetization were synthesized by a modified silanation method. Under geomagnetic field (5 × 10−5 T), with the increase of the saturation magnetizations, the growth rate of yields of cyclohexanol in the cyclohexane oxidation with iodosylbenzene catalyzed by these nanoparticle bonded metalloporphyrins followed the order of ironporphyrin > manganeseporphyrin > cobaltporphyrin.

Graphical Abstract

A series of nanoparticle bonded metalloporphyrins with different saturation magnetization were synthesized by a modified silanation method. Under geomagnetic field (5 × 10−5 T), with the increase of the saturation magnetizations, the growth rate of yields of cyclohexanol in the cyclohexane oxidation with iodosylbenzene catalyzed by these nanoparticle bonded metalloporphyrins followed the order of ironporphyrin > manganeseporphyrin > cobaltporphyrin.

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Acknowledgement

The authors gratefully thank the financial supports of National Natural Science Foundation of China (Grants CN J0830415).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Hunan University, 410082, Changsha, China

    Chang-Xiang Liu, Qiang Liu & Can-Cheng Guo

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  1. Chang-Xiang Liu
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  2. Qiang Liu
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  3. Can-Cheng Guo
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Correspondence to Can-Cheng Guo.

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Liu, CX., Liu, Q. & Guo, CC. Synthesis and Catalytic Abilities of Silica-coated Fe3O4 Nanoparticle Bonded Metalloporphyrins with Different Saturation Magnetization. Catal Lett 138, 96–103 (2010). https://doi.org/10.1007/s10562-010-0379-z

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  • DOI: https://doi.org/10.1007/s10562-010-0379-z

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