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Catalysis Letters

, Volume 130, Issue 3–4, pp 296–300 | Cite as

Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen over Palladium Catalyst Supported on SO3H-Functionalized SBA-15

  • Sunyoung Park
  • Tae Jin Kim
  • Young-Min Chung
  • Seung-Hoon Oh
  • In Kyu Song
Article

Abstract

Palladium catalyst supported on SO3H-functionalized SBA-15 (denoted as Pd/SO3H-SBA-15) was applied to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. For comparison, palladium catalyst supported on SBA-15 (denoted as Pd/SBA-15) was also employed for the direct synthesis of hydrogen peroxide. Selectivity for hydrogen peroxide, yield for hydrogen peroxide, and final concentration of hydrogen peroxide over Pd/SO3H-SBA-15 catalyst were much higher than those over Pd/SBA-15 catalyst. The high catalytic performance of Pd/SO3H-SBA-15 catalyst was attributed to the enhanced acid amount of SO3H-SBA-15 support, which served as an alternate acid source in the direct synthesis of hydrogen peroxide from hydrogen and oxygen.

Keywords

Hydrogen peroxide Palladium catalyst SO3H-functionalized SBA-15 

Notes

Acknowledgments

The authors wish to acknowledge supports from Ministry of Knowledge Economy and SK Energy Corporation.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Sunyoung Park
    • 1
  • Tae Jin Kim
    • 2
  • Young-Min Chung
    • 2
  • Seung-Hoon Oh
    • 2
  • In Kyu Song
    • 1
  1. 1.School of Chemical and Biological Engineering, Institute of Chemical ProcessesSeoul National UniversityKwanak-ku, SeoulSouth Korea
  2. 2.SK Energy CorporationDaejeonSouth Korea

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