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Catalysis Letters

, Volume 130, Issue 1–2, pp 239–245 | Cite as

Development of a Catalytic Cycle in Molybdenum Carbide Catalyzed NO/CO Reaction

  • Zhiwei Yao
  • Chuan Shi
Article

Abstract

In NO/CO reaction, there is a competition between NO reduction by CO and Mo2C oxidation by oxygen generated during NO dissociation. A complete equality of NO conversion and NO reduction degree can be achieved after increasing CO concentration in the system, which makes establishing a catalytic cycle on Mo2C catalyst possible.

Keywords

Mo2NO reduction NO dissociation Catalytic cycle 

Notes

Acknowledgments

The work was supported by the National Natural Science Foundation of China (No. 20573014) and by the Program for New Century Excellent Talents in University (NCET-07-0136).

References

  1. 1.
    Smeets PJ, Groothaert MH, van Teeffelen RM, Leeman H, Hensen EJM, Schoonheydt RA (2007) J Catal 245:358CrossRefGoogle Scholar
  2. 2.
    Kustova MY, Rasmussen SB, Kustov AL, Christensen CH (2006) Appl Catal B 67:60CrossRefGoogle Scholar
  3. 3.
    Wang C, Wang X, Xing N, Yu Q, Wang Y (2008) Appl Catal A 334:137CrossRefGoogle Scholar
  4. 4.
    Wang X, Sigmon SM, Spivey JJ, Henry Lamb H (2004) Catal Today 96:11CrossRefGoogle Scholar
  5. 5.
    Li L, Zhang F, Guan N, Schreier E, Richter M (2008) Catal Commun 9:1827CrossRefGoogle Scholar
  6. 6.
    Kotsifa A, Kondarides DI, Verykios XE (2008) Appl Catal B 80:260CrossRefGoogle Scholar
  7. 7.
    Galvez ME, Boyano A, Lazaro MJ, Moliner R (2008) Chem Eng J 144:10CrossRefGoogle Scholar
  8. 8.
    Iwakuni H, Shinmyou Y, Yano H, Matsumoto H, Ishihara T (2007) Appl Catal B 74:299CrossRefGoogle Scholar
  9. 9.
    Zhang Z, Geng H, Zheng L, Du B (2005) J Alloys Compd 392:317CrossRefGoogle Scholar
  10. 10.
    Haneda M, Kintaichi Y, Nakamura I, Fujitani T, Hamada H (2002) Chem Commun p 2816Google Scholar
  11. 11.
    Naito S, Iwahashi M, Kawakami I, Miyao T (2002) Catal Today 73:355CrossRefGoogle Scholar
  12. 12.
    Haneda M, Kintaichi Y, Nakamura I, Fujitani T, Hamada H (2003) J Catal 218:405CrossRefGoogle Scholar
  13. 13.
    Patterson PM, Das TK, Davis BH (2003) Appl Catal A 251:449CrossRefGoogle Scholar
  14. 14.
    Kojima R, Aika K (2001) Appl Catal A 219:141CrossRefGoogle Scholar
  15. 15.
    Tominaga H, Nagai M (2007) Appl Catal A 328:35CrossRefGoogle Scholar
  16. 16.
    Pritchard ML, Mclauley RL, Gallaher BN, Thomson WJ (2004) Appl Catal A 275:213CrossRefGoogle Scholar
  17. 17.
    Li S, Lee JS, Hyeon T, Suslick KS (1999) Appl Catal A 184:1CrossRefGoogle Scholar
  18. 18.
    Szymańska-Koalsa A, Lewandowski M, Sayag C, Djéga-Mariadassou G (2007) Catal Today 119:7CrossRefGoogle Scholar
  19. 19.
    Lewandowski M, Szymańska-Koalsa A, Da Costa P, Sayag C (2007) Catal Today 119:31CrossRefGoogle Scholar
  20. 20.
    Wang J, Castonguay M, Deng J, McBreen PH (1997) Surf Sci 374:197CrossRefGoogle Scholar
  21. 21.
    Zhang M, Hwu HH, Buelow MT, Chen JG, Ballinger TH, Andersen PJ (2001) Catal Lett 77:29CrossRefGoogle Scholar
  22. 22.
    Wang J, Ji S, Yang J, Zhu Q, Li S (2005) Catal Commun 6:389CrossRefGoogle Scholar
  23. 23.
    Neylon MK, Choi S, Kwon H, Curry KE, Thompson LT (1999) Appl Catal A 183:253CrossRefGoogle Scholar
  24. 24.
    Liang C, Ma W, Feng Z, Li C (2003) Carbon 41:1833CrossRefGoogle Scholar
  25. 25.
    Zhang MH, Hwu HH, Buelow MT, Chen JG, Ballinger TH, Andersen PJ, Mullins DR (2003) Surf Sci 522:112CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.Laboratory of Plasma Physical ChemistryDalian University of TechnologyDalianPeople’s Republic of China
  2. 2.State Key Laboratory of Fine chemicalsDalian University of TechnologyDalianPeople’s Republic of China

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