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Development of a Catalytic Cycle in Molybdenum Carbide Catalyzed NO/CO Reaction

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Abstract

In NO/CO reaction, there is a competition between NO reduction by CO and Mo2C oxidation by oxygen generated during NO dissociation. A complete equality of NO conversion and NO reduction degree can be achieved after increasing CO concentration in the system, which makes establishing a catalytic cycle on Mo2C catalyst possible.

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Acknowledgments

The work was supported by the National Natural Science Foundation of China (No. 20573014) and by the Program for New Century Excellent Talents in University (NCET-07-0136).

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Authors and Affiliations

  1. Laboratory of Plasma Physical Chemistry, Dalian University of Technology, 116024, Dalian, People’s Republic of China

    Zhiwei Yao & Chuan Shi

  2. State Key Laboratory of Fine chemicals, Dalian University of Technology, 116024, Dalian, People’s Republic of China

    Chuan Shi

Authors
  1. Zhiwei Yao
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  2. Chuan Shi
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Correspondence to Chuan Shi.

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Yao, Z., Shi, C. Development of a Catalytic Cycle in Molybdenum Carbide Catalyzed NO/CO Reaction. Catal Lett 130, 239–245 (2009). https://doi.org/10.1007/s10562-009-9875-4

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  • DOI: https://doi.org/10.1007/s10562-009-9875-4

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