Catalysis Letters

, Volume 130, Issue 1–2, pp 137–146 | Cite as

Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene

  • Lan Ma
  • Qingrong Peng
  • Dehua He


An amorphous Co-B catalyst was prepared by chemical reduction method and characterized by isothermal N2 adsorption/desorption, XRD, ICP-AES and HR-TEM. The catalytic activity of the Co-B catalyst in the hydroformylation of 1-octene was evaluated in a 100 mL stainless autoclave. Fresh amorphous Co-B catalyst showed a relatively high activity in the hydroformylation of 1-octene. The thermal stability of fresh Co-B catalyst was also examined. When fresh Co-B catalyst was thermally treated in N2 or H2 atmosphere at 200–500 °C for 2 h, the specific surface area and the catalytic activity of the Co-B catalyst decreased. When Co-B was supported on SiO2, the activity of the catalyst increased obviously. Compared with conventional supported Co/SiO2 catalyst, Co-B/SiO2 showed much higher activity than Co/SiO2. The influences of solvents and reaction conditions on the catalytic activity of the amorphous Co-B catalyst were also studied. The recycle test of the amorphous Co-B catalyst was done.


Hydroformylation 1-Octene Nonyl aldehyde Amorphous Co-B 



This work is supported by the National Natural Science Foundation of China (20373031) and the Analytical Foundation of Tsinghua University, China.


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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.Innovative Catalysis Program, Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of ChemistryTsinghua UniversityBeijingChina
  2. 2.Institute of Chemical DefenceBeijingChina

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