Abstract
Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy was used to study the nature of active species in K–Rh–Co–MoS2/Al2O3 catalyst by means of probing with CO molecule. The effects of K addition to Rh and interaction between Mo and Rh were studied with varying K and Mo loadings over 1 wt% Rh/Al2O3 catalyst. In sulfided Rh–Mo/Al2O3, the formation of Rh–Mo–S phase was evidenced first time by a band at 2,095 cm−1. The introduction of Co to K–Rh–MoS2/Al2O3 catalyst showed the existence of both Rh and Co promoted MoS2 sites, but the CO absorption frequencies in DRIFT spectra are significantly at lower side compared to Co free Rh–Mo catalyst. The stabilities of CO band from Rh and Co promoted and unpromoted MoS2 sites are studied at different temperatures. When activated carbon used as support, bands for both promoted and unpromoted MoS2 sites were appeared, but the intensity of these bands were decreased largely compared to alumina based catalyst, resulted from the coverage of added K not only on the support surface but also on the active metal components due to the neutral nature of activated carbon.
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Murchison CB, Conway MM, Stevens RR, Quarderer CJ (1988) In: Phillips MJ, Ternan M (eds) Proceedings of 9th International Congress on Catalysis, vol 2, Calgary, Chemical Institute of Canada, Ottawa, p 626
Santiesteban JC, Boogdan CE, Herman RG, Klier K (1988) In: Phillips MJ, Ternan M (eds) Proceedings of 9th International Congress on Catalysis, vol 2, Calgary, Chemical Institute of Canada, Ottawa
Xu X, Doesburg EBM, Scholten JJF (1987) Catal Today 2:125
Natta G, Colombo U, Pasquon I (1957) In: Catalysis, vol 131, ed. Emmett
Iranmahboob J, Hill DO (2002) Catal Letters 78:49
Xie Y, Naasz BM, Somorjai GA (1986) Appl Catal 27:233
Lee JS, Kim S, Lee KH, Nam IS, Chung JS, Kim YG, Woo HC (1994) Appl Catal A 110:11
Shen JY, Matsuzaki T, Hanaoka T, Takeuchi K, Sugi Y (1994) Catal Letters 28:329
Li Z, Fu Y, Bao J, Jiang M, Hu T, Liu T, Xie Y-n (2001) Appl Catal A 220:21
Knifton JF, Lin JJ, Storm DA, Wong SF (1993) Catal Today 18:355
Fujumoto A, Oba T (1985) Appl Catal 13:289
Te M, Lowenthal EE, Foley HC (1994) Chem Eng Sci 49:4851
Storm DA (1995) Top Catal 2:91
Wong SF, Storm DA, Patel MS, US Patents 4 980 380, 1990 and 4 983 638, 1991, to Texaco
Li Z-r, Fu Y-l, Jiang M (1999) Appl Catal A 187:187
Sudhakar C, Bhore NA, Bischoff KB, Manogue WH, Mills GA (1987) Proceedings of 10th Meeting of the Catalysis Society of North America, San Diego, CA
Foley HC, Hong AJ, Brinen JS, Allard LF, Garratt-Reed AJ (1990) Appl Catal 61:351
Yang AC, Garland CW (1957) J Phys Chem 61:1504
Yates JT Jr, Duncan TM, Vaughan RW (1979) J Chem Phys 71:3908
Yates JT Jr, Duncan TM, Worley SD, Vaughan RW (1979) J Chem Phys 70:1219
van’t Blik HFJ, van Zon JBAD, Huizinga T, Vis JC, Koningsberger DC, Prins R (1985) J Am Chem Soc 107:3139
Yates DJC, Murell LL, Prestridge EB (1979) J Catal 57:41
Solymosi F, Pasztor M (1986) J Phy Chem 90:5312
Basu P, Panayotov D Jr, Yates JT (1988) J Am Chem Soc 110:2074
Berko A, Menesi G, Solymosi F (1997) Surf Sci 372:202
Berko A, Menesi G, Solymosi F (1996) J Phys Chem 100:17732
Storm DA, Mertens FP, Cataldo MC, DeCanio EC (1993) J Catal 141:478
Wardinsky MD, Hecker WC (1988) J Phys Chem 92:2602
DeCanio EC, Storm DA (1991) J Catal 132:375
Mills GA (1994) Summary of the higher alcohols synthesis workshop, B. R. Service Corporation
Koizumi N, Bian G, Murai K, Ozaki T, Yamada M (2004) J Mol Catal A 207:171
Worley SD, Rice CA, Mattson GA, Curtis CW, Guin JA, Tarrer AR (1982) J Chem Phys 76:20
Lafaye G, Mihut C, Especel C, Marecot P, Amiridis MD (2004) Langmuir 20:10612
Wang Y, Du S (2001) React Kinet Catal Lett 73:381
Praliaud A, Primet M, Martin GA (1983) Appl Surf Sci 17:107
Van’t Blik HFJ, Van Zon JBAD, Huizinga T, Vis JC, Koningsberger DC, Prins R (1983) J Phys Chem 87:2264
Solymosi F, Tombacz I, Kocsis M (1982) J Catal 75:78
Solymosi F, Pasztor M (1985) J Phys Chem 84:4789
Davydov AA (1990) Infrared spectroscopy of adsorbed species on the surface of transition metal oxides. Wiley, London
van den Berg FGA, Glezer JHE, Sachtler WMH (1985) J Catal 93:340
Jiang M, Bian G-Z, Fu Y-L (1994) J Catal 146:144
Kip BJ, Hermans EGF, Van Wolput JHMC, Hermans NMA, Van Grondelle J, Prins R (1987) Appl Catal 35:109
Gulielminotti E, Giamello E, Pinna F, Strukul G, Martinengo S, Zanderighi L (1993) In: Guczi L, Solymosi E, Tetenyi P (eds) New frontiers in catalysis. Elsevier, Amsterdam
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The financial support by Natural Sciences and Engineering Research Council (NSERC) of Canada to Dr. A. K. Dalai for this work is gratefully acknowledged.
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Eswaramoorthi, I., Dalai, A.K. DRIFT Studies of Adsorbed CO Over Sulfided K–Rh–Mo/Al2O3 Catalysts: Detection of Rh–Mo–S Phase. Catal Lett 131, 203–212 (2009). https://doi.org/10.1007/s10562-009-0037-5
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DOI: https://doi.org/10.1007/s10562-009-0037-5