Skip to main content
SpringerLink
Log in

Development of Stable and Highly Active Bimetallic Ni–Au Catalysts Supported on Binary Oxides CrAl3O6 for POM Reaction

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The resistance of supported Ni catalysts for carbon deactivation in CH4 partial oxidation (POM) was studied in this work. The 5%Ni/Al2O3 catalyst showed only 18% of CH4 conversion at 900 °C and 23% carbon deposition after 24 h run of POM. Both Au addition and binary support CrAl3O6 use seem to guarantee high activity (100% at 900 °C), selectivity (97% at 900 °C) and high carbon resistance (<1%). Furthermore the gold doped catalysts revealed only the presence of Cα and Cβ whereas the monometallic Ni catalysts showed the presence of graphitic carbon Cγ responsible for catalysts deactivation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Ohi T, Miyata T, Li D, Shishido T, Kawabata T, Sano T, Takehira K (2006) Appl Cat A 308:194

    Article  CAS  Google Scholar 

  2. Lucredio AF, Jerkiewick G, Assaf EM (2007) Appl Cat A 333:90

    Article  CAS  Google Scholar 

  3. Nikolla E, Shwank J, Linic S (2007) J Cat 250:85

    Article  CAS  Google Scholar 

  4. Molenbroek AM, Norskov JK (2001) J Phys Chem B 105:5450

    Article  CAS  Google Scholar 

  5. Miyata T, Li D, Shiraga M, Shishido T, Oumi Y, Sano T, Takehira K (2006) Appl Catal 310:97

    Article  CAS  Google Scholar 

  6. Witońska I, Maniecki TP (2007) Przem Chem 86/11:2

    Google Scholar 

  7. Maniecki TP, Bawolak K, Mierczyński P, Jóźwiak WK (2008) Polish J Chem 82:2245

    Google Scholar 

  8. Maniecki TP, Bawolak K, Gebauer D, Jóźwiak WK (2007) Przem Chem 869:857

    Google Scholar 

  9. Maniecki TP, Rogowski J, Bawolak K, Nowosielska M, Jóźwiak W, Polish J (2006) Environ Stud 15.6A:124

    Google Scholar 

  10. Besenbacher F, Chorkendorff I, Clausen BS, Hammer B, Molenbroek AM, Norskov JK, Stensgaard I (1998) Science 279:1913

    Article  CAS  Google Scholar 

  11. Ruban AV, Skriver HL, Norskov JK (1999) Phys Rev B 59:15990

    Article  Google Scholar 

  12. Djaidja A, Libs S, Kiennemann A, Barama A (2006) Catal Today 113:194

    Article  CAS  Google Scholar 

  13. Maniecki TP, Bawolak K, Gebauer D, Mierczynski P, Jozwiak WK, KinCat (in a print)

  14. Zhang ZL, Verykios XE (1994) Catal Today 21(2–3):589

    Article  CAS  Google Scholar 

  15. Guo J, Lou H, Zheng X (2007) Carbon 45:1314

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The financial support of this work by the Polish Scientific Research Council supports (Grant No. 1357/T09/2005/29) is gratefully acknowledged.

Author information

Authors and Affiliations

  1. Technical University of Lodz, 94-924, Lodz, Poland

    Tomasz P. Maniecki, Katarzyna Bawolak, P. Mierczyński & Wojciech K. Jozwiak

Authors
  1. Tomasz P. Maniecki
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Katarzyna Bawolak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Mierczyński
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wojciech K. Jozwiak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Katarzyna Bawolak.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Maniecki, T.P., Bawolak, K., Mierczyński, P. et al. Development of Stable and Highly Active Bimetallic Ni–Au Catalysts Supported on Binary Oxides CrAl3O6 for POM Reaction. Catal Lett 128, 401–404 (2009). https://doi.org/10.1007/s10562-008-9763-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-008-9763-3

Keywords

Search

Navigation