Skip to main content

Advertisement

SpringerLink
Log in

A Possible Mechanism of Hydrogen Reverse Spillover in Platinum-Zeolite Catalysts

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Quantum chemical methods (X3LYP and MP2) were applied to investigate the structure and reactivity of anion-radical site in HZSM-5 zeolite. The interaction of hydrogen zeolite with a platinum particle can involve electron transfer to a Brønsted acid site to form an anion-radical fragment. A low stability of the latter favors the elimination of atomic hydrogen from the OH-group, an exothermic process with low activation energy. In the metal-zeolite catalysts, the anion-radical fragment formed due to withdrawal of electronic density from the metal particle can be responsible for the reverse spillover of Brønsted hydrogen onto the metal surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Weisz PB, Swegler EW (1957) Science 126:31

    Article  CAS  Google Scholar 

  2. Kuhlmann A, Rössner F, Schwieger W, Gravenhorst O, Selvam T (2004) Catal Today 97:303

    Article  CAS  Google Scholar 

  3. Ono Y (2003) Catal Today 81:3

    Article  CAS  Google Scholar 

  4. Steinberg K-H, Hofmann F, Bremer H, Dmitriev RV, Detjuk AN, Minachev KhM (1979) Z Chem 19:34

    CAS  Google Scholar 

  5. Minachev KhM, Dmitriev RV, Detyuk AN, Steinberg K-H, Bremer H (1978) Bull Acad Sci USSR Div Chem Sci 27:2394

    Article  Google Scholar 

  6. Mikhailov MN, Kustov LM, Kazansky VB (2008) Catal Lett 120:8

    Article  CAS  Google Scholar 

  7. Mikhailov MN, Mishin IV, Kustov LM, Microporous Mesoporous Mater. doi 10.1016/j.micromeso.2008.08.014

  8. Mikhailov MN, Mishin IV, Kustov LM, Mordkovich VZ (2009) Catal Today (in press)

  9. Mikhailov MN, Kustov LM, Mordkovich VZ, Stakheev AYu (2008) Russ Chem Bull 57 (in press)

  10. Kramer GJ, van Santen RA (1993) J Am Chem Soc 115:2887

    Article  CAS  Google Scholar 

  11. Brand HV, Curtiss LA, Iton LE (1993) J Phys Chem 97:12773

    Article  CAS  Google Scholar 

  12. Brand HV, Curtiss LA, Iton LE (1992) J Phys Chem 96:7725

    Article  CAS  Google Scholar 

  13. Redondo A, Hay PJ (1993) J Phys Chem 97:11754

    Article  CAS  Google Scholar 

  14. Xu X, Zhang Q, Muller RP, Goddard WAIII (2005) J Chem Phys 122:014105

    Article  Google Scholar 

  15. Schmidt MW, Baldridge KK, Boatz JA et al (1993) J Comput Chem 14:1347

    Article  CAS  Google Scholar 

  16. Granovsky AA, PC GAMESS version 7.1. http://classic.chem.msu.su/gran/gamess/index.html

  17. Yuan SP, Wang JG, Li YW, Jiao H (2002) J Phys Chem A 106:8167

    Article  CAS  Google Scholar 

  18. Barone G, Casella G, Giuffrida S, Duca D (2007) J Phys Chem C 111:13033

    Article  CAS  Google Scholar 

  19. Slinkin AA, Kucherov AV, Kondratyev DA, Bondarenko TN, Rubinstein AM, Minachev KhM (1986) J Mol Catal 35:97

    Article  CAS  Google Scholar 

  20. Kucherov AV, Slinkin AA, Kondratyev DA, Bondarenko TN, Rubinstein AM, Minachev KhM (1986) J Mol Catal 37:107

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the critical reading of the manuscript by Dr. Walter H. Niehoff.

Author information

Authors and Affiliations

  1. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Russian Federation, Leninsky Prospect 47, 119991, Moscow, Russia

    M. N. Mikhailov, I. V. Mishin & L. M. Kustov

Authors
  1. M. N. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. V. Mishin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. M. Kustov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. N. Mikhailov.

Additional information

This paper is dedicated to the memory of Professor Heinrich Bremer (1920–2008).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikhailov, M.N., Mishin, I.V. & Kustov, L.M. A Possible Mechanism of Hydrogen Reverse Spillover in Platinum-Zeolite Catalysts. Catal Lett 128, 313–317 (2009). https://doi.org/10.1007/s10562-008-9757-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-008-9757-1

Keywords

Search

Navigation