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Tungsten Oxides-Containing Titanium Silicalite for Liquid Phase Epoxidation of 1-octene with Aqueous Hydrogen Peroxide

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Abstract

Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts.

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Acknowledgments

We gratefully acknowledge funding from the Ministry of Science Technology and Innovation Malaysia (MOSTI), under IRPA grant No. 09-02-06-0057 SR0005/09-03 and Directorate General of Higher Education, Indonesia, under Hibah Kompetensi grant No. 1108/I2.7/PM/2008.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Mathematic and Sciences, Institut Teknologi Sepuluh Nopember (ITS), Surabaya, 60111, Indonesia

    Didik Prasetyoko & Hamzah Fansuri

  2. Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310, Johor, Malaysia

    Zainab Ramli & Salasiah Endud

  3. Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, 81310, Johor, Malaysia

    Hadi Nur

Authors
  1. Didik Prasetyoko
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  2. Hamzah Fansuri
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  3. Zainab Ramli
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  4. Salasiah Endud
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  5. Hadi Nur
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Correspondence to Didik Prasetyoko.

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Prasetyoko, D., Fansuri, H., Ramli, Z. et al. Tungsten Oxides-Containing Titanium Silicalite for Liquid Phase Epoxidation of 1-octene with Aqueous Hydrogen Peroxide. Catal Lett 128, 177–182 (2009). https://doi.org/10.1007/s10562-008-9727-7

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  • DOI: https://doi.org/10.1007/s10562-008-9727-7

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