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1-Hexene Double Bond Isomerization Reaction Over SO =4 Promoted NiO, Al2O3 and ZrO2 Acid Catalysts

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Abstract

Sulfated mixed oxides, SO =4 /Ni–Al–O and SO =4 /Zr–Al–O were evaluated for double bond isomerization (DBI) of 1-hexene using helium and hydrogen as carrier gases. The increase of temperature from 100 to 200 °C seems to favor the deprotonation pathway and contribute to increase the 1-hexene conversion for both catalysts and without regard of the carrier gas. The results indicate that temperature it is the main factor that contributes to improve both conversion and selectivity towards (cis + trans)-2-hexene, while the reductive atmosphere beneficiate only the SO =4 /Ni–Al–O catalyst performance, as hydrogen prevents this catalyst from a fast deactivation.

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Authors and Affiliations

  1. Instituto Mexicano del Petroleo, Eje Central Lázaro Cárdenas # 152, 07730, Mexico, D.F., Mexico

    M. Pérez-Luna, A. Cosultchi, J. A. Toledo-Antonio & L. Díaz-Garcia

  2. Department of Metallurgical Engineering-ESIQIE, Instituto Politécnico Nacional, Zacatenco, 07738, Mexico, D.F., Mexico

    M. Pérez-Luna

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  1. M. Pérez-Luna
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  2. A. Cosultchi
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  3. J. A. Toledo-Antonio
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  4. L. Díaz-Garcia
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Correspondence to M. Pérez-Luna.

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Pérez-Luna, M., Cosultchi, A., Toledo-Antonio, J.A. et al. 1-Hexene Double Bond Isomerization Reaction Over SO =4 Promoted NiO, Al2O3 and ZrO2 Acid Catalysts. Catal Lett 128, 290–296 (2009). https://doi.org/10.1007/s10562-008-9714-z

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  • DOI: https://doi.org/10.1007/s10562-008-9714-z

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