Skip to main content
SpringerLink
Log in

Application of Conjugated Polymer–Platinum Group Metal Composites as Heterogeneous Catalysts

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Composites of polyaniline (PANI) or polypyrrole (PPy) doped with chloride ions and Pt or Rh particles were prepared by chemical reduction of metal ions conducted in the presence of the polymers. Based on X-ray diffraction studies it was established that the composites contained metal nanoparticles (5–9 in size). However, according to SEM investigations metal particles were agglomerated (40 nm–1.1 μm in size). Redox activity of the composites in the catalytic isopropyl alcohol conversion was ca. ten times higher than the acid–base one. Pt dispersed in polymer matrices showed higher catalytic activity than Rh. PPy doped with chloride ions had a promoting effect on the activity of Pt catalysts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Shirakawa H, Lewis EJ, MacDiarmid AG, Chiang CK, Heeger AJ (1977) J Chem Soc Chem Commun 578

  2. Stenger-Smith JD (1998) Prog Polym Sci 23:57

    Article  CAS  Google Scholar 

  3. McQuade DT, Pullen AE, Swager TM (2000) Chem Rev 100:2537

    Article  CAS  Google Scholar 

  4. Pron A, Rannou P (2002) Prog Polym Sci 27:135

    Article  CAS  Google Scholar 

  5. Palaniappan S, John A (2008) Curr Org Chem 12:98

    Article  CAS  Google Scholar 

  6. Turek W, Lapkowski M, Debiec J, Krowiak A (2005) Appl Surf Sci 252:847

    Article  CAS  Google Scholar 

  7. Lim SS, Park GI, Choi JS, Song IK, Lee WY (2002) Catal Today 74:299

    Article  CAS  Google Scholar 

  8. Laborde H, Léger J-M, Lamy C (1994) J Appl Electrochem 24:219

    CAS  Google Scholar 

  9. Hepel M (1998) J Electrochem Soc 145:124

    Article  CAS  Google Scholar 

  10. Bouzek K, Mangold K-M, Jüttner K (2001) J Appl Electrochem 31:501

    Article  CAS  Google Scholar 

  11. Gholamian M, Sundaram J, Contarctor AQ (1987) Langmuir 3:741

    Article  CAS  Google Scholar 

  12. Maksimov YuM, Kolyadko EA, Shishlova AV, Podlovchenko BI (2001) Russ J Electrochem 37:777

    Article  CAS  Google Scholar 

  13. Houdayer A, Schneider R, Billaud D, Ghanbaja J, Lambert J (2005) Appl Organomet Chem 19:1239

    Article  CAS  Google Scholar 

  14. Amaya T, Saio D, Hirao T (2007) Tetrahedron Lett 48:2729

    Article  CAS  Google Scholar 

  15. Dodouche I, Epron F (2007) Appl Catal B: Environ 76:291

    Article  CAS  Google Scholar 

  16. Gallon BJ, Kojima RW, Kaner RB, Diaconescu PL (2007) Angew Chem Int Ed 46:7251

    Article  CAS  Google Scholar 

  17. Steffan M, Klasovsky F, Arras J, Roth C, Radnik J, Hofmeister H, Claus P (2008) Adv Synth Catal 350:1337

    Article  CAS  Google Scholar 

  18. Stochmal E, Hasik M, Adamczyk A, Bernasik A, Turek W, Sniechota A (2008) J Appl Polym Sci 108:447

    Article  CAS  Google Scholar 

  19. Elizarova GL, Matvenko LG (1970) Zh Anal Khim 25:301

    CAS  Google Scholar 

  20. Berg EW, Youmans HL (1961) Anal Chim Acta 22:231

    Google Scholar 

  21. NIST Standard Reference Database 20, Version 3.5 (Web Version), released August 2003 (www.nist.gov)

  22. MacDiarmid AG, Epstein AJ (1989) Faraday Discuss Chem Soc 88:317

    Article  CAS  Google Scholar 

  23. Saunders BR, Fleming RJ, Murray KS (1995) Chem Mater 7:1082

    Article  CAS  Google Scholar 

  24. Kang ET, Neoh KG, Ong YK, Tan KL, Tan BTG (1991) Macromolecules 24:2822

    Article  CAS  Google Scholar 

  25. Voogt EH, Mens AJM, Gijzeman OLJ, Geus JW (1999) Catal Today 47:321

    Article  CAS  Google Scholar 

  26. JCPDS–International Centre for Diffraction Data, database 2002 (www.icdd.com), files: 05-0685 (Rh) and 04-0802 (Pt)

  27. Pouget JP, Jozefowicz ME, Epstein AJ, Tang X, MacDiarmid AG (1991) Macromolecules 24:779

    Article  CAS  Google Scholar 

  28. Turek W, Haber J, Krowiak A (2005) Appl Surf Sci 252:823

    Article  CAS  Google Scholar 

  29. Palaniappan S, Ram MS (2002) Green Chem 4:53

    Article  CAS  Google Scholar 

  30. Li Y, Ouyang J, Yang J (1995) Synth Met 74:49

    Article  CAS  Google Scholar 

Download references

Acknowledgments

XPS measurements have been performed in the Surface Spectroscopy Laboratory at the Department of Materials Science and Ceramics of AGH-University of Science and Technology in Krakow (Poland).

Author information

Authors and Affiliations

  1. Faculty of Materials Science and Ceramics, AGH-University of Science and Technology, Al. Mickiewicza 30, 30-059, Krakow, Poland

    Magdalena Hasik, Anna Nyczyk & Edyta Stochmal

  2. Department of Chemistry, Silesian Technical University, Ul. Strzody 9, 44-100, Gliwice, Poland

    Wincenty Turek, Agnieszka Sniechota & Agnieszka Sołtysek

  3. Faculty of Physics and Applied Computer Science, AGH-University of Science and Technology, Al. Mickiewicza 30, 30-059, Krakow, Poland

    Andrzej Bernasik

Authors
  1. Magdalena Hasik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wincenty Turek
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Anna Nyczyk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Edyta Stochmal
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Andrzej Bernasik
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Agnieszka Sniechota
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Agnieszka Sołtysek
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Magdalena Hasik.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hasik, M., Turek, W., Nyczyk, A. et al. Application of Conjugated Polymer–Platinum Group Metal Composites as Heterogeneous Catalysts. Catal Lett 127, 304–311 (2009). https://doi.org/10.1007/s10562-008-9679-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-008-9679-y

Keywords

Search

Navigation