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Preparation of Mesoporous Organically Modified Titanium Materials and their Activity in the Oxidation of Cyclohexene

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Abstract

Mesoporous organically modified Ti-MCM-41 materials were synthesised employing different Ti precursors. Materials were found to possess improved properties in terms of stability, hydrophobicity and activity compared to the parent Ti-MCM-41, preserving their mesoporous structural order. The organically modified mesoporous materials were tested in the oxidation of cyclohexene using conventional heating and microwaves. The microwave assisted protocol was found to enhance reaction rates and selectivities to the epoxide, reducing the times of reaction from 24 to less than 1 h at comparable activities (60–80% conversion).

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Authors and Affiliations

  1. Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie (C3), 14014, Cordoba, Spain

    Jose M. Hidalgo, Maria J. Jurado, Juan M. Campelo & Antonio A. Romero

  2. Department of Chemistry, Green Chemistry Centre of Excellence, The University of York, Heslington, YO10 5DD, York, UK

    Rafael Luque

Authors
  1. Jose M. Hidalgo
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  2. Maria J. Jurado
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  3. Juan M. Campelo
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  4. Rafael Luque
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  5. Antonio A. Romero
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Correspondence to Rafael Luque.

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Hidalgo, J.M., Jurado, M.J., Campelo, J.M. et al. Preparation of Mesoporous Organically Modified Titanium Materials and their Activity in the Oxidation of Cyclohexene. Catal Lett 126, 179–187 (2008). https://doi.org/10.1007/s10562-008-9602-6

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  • DOI: https://doi.org/10.1007/s10562-008-9602-6

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