Low-Pt Content Carbon-Supported Pt–Ni–TiO2 Nanotube Electrocatalyst for Direct Methanol Fuel Cells
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Low-Pt content (5%) carbon-supported Pt–Ni–TiO2 nanotube electrocatalysts were prepared via a microwave-assisted polyol strategy. Physical and morphological properties of these electrocatalysts were characterized by X-ray diffraction (XRD), high resolution transmission electron microscope (HRTEM), and energy dispersive X-ray spectroscopy (EDX). Cyclic voltammetry and chronoamperometry studies clearly suggested that the Pt(5%)–Ni(10%)–TiO2 nanotube (10%) supported by Vulcan XC-72 is better than the commercial 20% Pt/C electrocatalyst for methanol electro-oxidation in direct methanol fuel cells (DMFCs).
KeywordsPlatinum Nickel TiO2 nanotube Electrocatalyst Methanol electro-oxidation
This work was supported by the National High Technology Research and Development Program of China (2007AA05Z145), the National Basic Research Program of China (2003CB214504, 2007CB209705), and the Science & Technology Commission of Shanghai Municipality (06SN07115).
- 4.Liu HS, Song CJ, Zhang L, Zhang JJ, Wang HJ, Wilkinson DP (2006) J Power Source 155:95Google Scholar
- 8.Antolini E, Salgado JRC, Gonzalez ER (2006) J Power Source 155:161Google Scholar
- 13.Wu X, Jiang QZ, Ma ZF, Hu LQ (2007) Chin J Power Source 9:713Google Scholar
- 20.Wu X, Jiang QZ, Ma ZF, Shangguan WF (2006) Chin J Inorg Chem 22:341Google Scholar
- 22.Hogarth MP, Hards GA (1996) Plat Met Rev 40:150Google Scholar