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Catalysis Letters

, Volume 124, Issue 1–2, pp 127–132 | Cite as

Bismuth Subnitrate as an Efficient Heterogeneous Catalyst for Acetalization and Ketalization of Carbonyl Compounds with Diols

  • Shuisheng Wu
  • Weili Dai
  • Shuangfeng Yin
  • Wensheng Li
  • Chak-Tong Au
Article

Abstract

Bismuth subnitrate has been found to be an excellent catalyst for acetalization and ketalization of a wide range of aldehydes and ketones with diols under mild conditions. The catalyst remained in solid form throughout the reaction and could be readily reused and recycled without any loss of activity. It is deduced that the excellent performance of bismuth subnitrate may be ascribed to its acidity.

Keywords

Bismuth subnitrate Acetalization Ketalization Carbonyl compound Diol 

Notes

Acknowledgments

This work was financially supported by the National Science Foundation of China (No. 20507005).

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringHunan UniversityChangshaChina
  2. 2.Department of ChemistryHong Kong Baptist UniversityHong KongChina

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