Titanium–Silica Catalysts for the Production of Fully Epoxidised Fatty Acid Methyl Esters
Grafted titanium-containing mesoporous silica catalysts were used in the selective epoxidation of C-18 unsaturated fatty acid methyl esters (FAMEs). High yields in mono- and diepoxide derivatives were obtained under acid-free reaction conditions with TBHP as oxidant. Ti-MCM-41 showed the best performance in terms of activity over the three FAMEs. Easy separation of the desired products and recycling of the catalyst were demonstrated.
KeywordsFatty acid methyl ester Epoxidation Titanium catalyst Renewables Oleochemicals
Authors acknowledge Italian Ministry of University and Research for funding (PRIN 2006 programme; prot. no. 2006032544).
- 2.Guidotti M, Psaro R, Sgobba M, Ravasio N (2007) In: Centi G, van Santen RA (eds) Catalysis for renewables: from feedstock to energy production. Wiley-VCH, Weinheim, p 257Google Scholar
- 15.Guidotti M, Batonneau-Gener I, Gianotti E, Marchese L, Mignard S, Psaro R, Sgobba M, Ravasio N, Microp. Mesop. Mater. (2007) doi:10.1016/j.micromeso.2007.07.010