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Selective Synthesis of 1-butene through Positional Isomerisation of 2-butene over Mesoporous Silica MCM-41

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Abstract

A highly selective and active catalyst for the positional isomerisation of 2-butene into 1-butene has been developed by using a mesoporous silica, MCM-41. The yields of 1-butene as well as total conversion decrease when aluminium or lanthanum was added to the MCM-41 even though the amounts of acid sites increase. FT-IR spectra proved that the H site due to the silanol group may act as an active site for the positional isomerisation of 2-butene to 1-butene.

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Acknowledgments

This work was supported by Energy Technology R&D Grant of the Korea Energy Management Cooperation (2005-E-ID11-P-02-3-020).

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Authors and Affiliations

  1. Department of Chemical Engineering, Kongju National University, Gongju, Chungnam, 314-701, Korea

    Jong-Ki Jeon & Heejin Lee

  2. Division of Advanced Materials Engineering, Kongju National University, Gongju, Chungnam, 314-701, Korea

    Jin-Heong Yim

  3. Chemicals R&D Center, SK Corporation, Yuseong-gu, Daejeon, 305-712, Korea

    Yong Seung Kim & Seong Jun Lee

  4. Faculty of Environmental Engineering, University of Seoul, Dongdaemun-Gu, Seoul, 130-743, Korea

    Young-Kwon Park

  5. Department of Chemistry, Sungkyunkwan University, Suwon, 440-746, Korea

    Jeong Kuk Shon & Ji Man Kim

  6. SKKU Advanced Institute of Nanotechnology, Sungkyunkwan University, Suwon, 440-746, Korea

    Jeong Kuk Shon & Ji Man Kim

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  1. Jong-Ki Jeon
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  2. Heejin Lee
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  3. Jin-Heong Yim
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  4. Yong Seung Kim
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  5. Seong Jun Lee
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  7. Jeong Kuk Shon
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  8. Ji Man Kim
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Correspondence to Jong-Ki Jeon.

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Jeon, JK., Lee, H., Yim, JH. et al. Selective Synthesis of 1-butene through Positional Isomerisation of 2-butene over Mesoporous Silica MCM-41. Catal Lett 119, 179–184 (2007). https://doi.org/10.1007/s10562-007-9219-1

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  • DOI: https://doi.org/10.1007/s10562-007-9219-1

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