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Impact of Boron Modification on MCM-41-Supported Cobalt Catalysts for Hydrogenation of Carbon Monoxide

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Abstract

Boron modification on MCM-41-supported cobalt (Co) catalysts was found to decrease the catalyst activity during CO hydrogenation. The decreased activities were due to stronger support interaction between Co oxide species and the support with the presence of boron resulting in lower reducibility. However, based on methanation the selectivity to C2–C4 products slightly increased with low loading of boron.

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Acknowledgments

We thank the Thailand Research Fund (TRF) and the graduate school at Chulalongkorn University (90th Anniversary of CU under the Golden Jubilee Fund) for financial support of this project. Guidance of the MCM-41 preparation by Dr. Panpranot is greatly appreciated.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Center of Excellence on Catalysis and Catalytic Reaction Engineering, Chulalongkorn University, Bangkok, 10330, Thailand

    Pimchanok Tupabut, Bunjerd Jongsomjit & Piyasan Praserthdam

Authors
  1. Pimchanok Tupabut
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  2. Bunjerd Jongsomjit
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  3. Piyasan Praserthdam
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Correspondence to Bunjerd Jongsomjit.

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Tupabut, P., Jongsomjit, B. & Praserthdam, P. Impact of Boron Modification on MCM-41-Supported Cobalt Catalysts for Hydrogenation of Carbon Monoxide. Catal Lett 118, 195–202 (2007). https://doi.org/10.1007/s10562-007-9160-3

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  • DOI: https://doi.org/10.1007/s10562-007-9160-3

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